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catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate]
The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex molecules and two solvent molecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the hete...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051769/ https://www.ncbi.nlm.nih.gov/pubmed/21522850 http://dx.doi.org/10.1107/S1600536811000304 |
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author | Zhao, Gan-Qing Li, Xu-Dong Han, Yong-Jun Xue, Ling-Wei Peng, Qin-Long |
author_facet | Zhao, Gan-Qing Li, Xu-Dong Han, Yong-Jun Xue, Ling-Wei Peng, Qin-Long |
author_sort | Zhao, Gan-Qing |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex molecules and two solvent molecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the heterocycle in the basal positions and one carboxylate O atom from a neighbouring ligand in the apical position. The apical Cu—O bonds are much longer than the basal Cu—O and Cu—N bonds. The carboxylate groups of the Schiff base ligands bridge the Cu(II) ions, forming helical chains along [100]. The crystal packing is stabilized by intermolecular O—H⋯O and N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3051769 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30517692011-04-26 catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] Zhao, Gan-Qing Li, Xu-Dong Han, Yong-Jun Xue, Ling-Wei Peng, Qin-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex molecules and two solvent molecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the heterocycle in the basal positions and one carboxylate O atom from a neighbouring ligand in the apical position. The apical Cu—O bonds are much longer than the basal Cu—O and Cu—N bonds. The carboxylate groups of the Schiff base ligands bridge the Cu(II) ions, forming helical chains along [100]. The crystal packing is stabilized by intermolecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051769/ /pubmed/21522850 http://dx.doi.org/10.1107/S1600536811000304 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhao, Gan-Qing Li, Xu-Dong Han, Yong-Jun Xue, Ling-Wei Peng, Qin-Long catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title |
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title_full |
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title_fullStr |
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title_full_unstemmed |
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title_short |
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)copper(II)]-μ-{N-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
title_sort | catena-poly[[[(3,5-dimethyl-1h-pyrazole)copper(ii)]-μ-{n-[1-(2-oxidophenyl)ethylidene]-l-valinato}] methanol monosolvate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051769/ https://www.ncbi.nlm.nih.gov/pubmed/21522850 http://dx.doi.org/10.1107/S1600536811000304 |
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