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catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]

The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex mol­ecules and two solvent mol­ecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the hete...

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Autores principales: Zhao, Gan-Qing, Li, Xu-Dong, Han, Yong-Jun, Xue, Ling-Wei, Peng, Qin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051769/
https://www.ncbi.nlm.nih.gov/pubmed/21522850
http://dx.doi.org/10.1107/S1600536811000304
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author Zhao, Gan-Qing
Li, Xu-Dong
Han, Yong-Jun
Xue, Ling-Wei
Peng, Qin-Long
author_facet Zhao, Gan-Qing
Li, Xu-Dong
Han, Yong-Jun
Xue, Ling-Wei
Peng, Qin-Long
author_sort Zhao, Gan-Qing
collection PubMed
description The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex mol­ecules and two solvent mol­ecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the heterocycle in the basal positions and one carboxyl­ate O atom from a neighbouring ligand in the apical position. The apical Cu—O bonds are much longer than the basal Cu—O and Cu—N bonds. The carboxyl­ate groups of the Schiff base ligands bridge the Cu(II) ions, forming helical chains along [100]. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-30517692011-04-26 catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate] Zhao, Gan-Qing Li, Xu-Dong Han, Yong-Jun Xue, Ling-Wei Peng, Qin-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(13)H(15)NO(3))(C(5)H(8)N(2))]·CH(3)OH}(n), contains two complex mol­ecules and two solvent mol­ecules. Each Cu(II) ion is in a distorted square-pyramidal coordination with one N and two O atoms from the Schiff base ligand and one N atom from the heterocycle in the basal positions and one carboxyl­ate O atom from a neighbouring ligand in the apical position. The apical Cu—O bonds are much longer than the basal Cu—O and Cu—N bonds. The carboxyl­ate groups of the Schiff base ligands bridge the Cu(II) ions, forming helical chains along [100]. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051769/ /pubmed/21522850 http://dx.doi.org/10.1107/S1600536811000304 Text en © Zhao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Gan-Qing
Li, Xu-Dong
Han, Yong-Jun
Xue, Ling-Wei
Peng, Qin-Long
catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title_full catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title_fullStr catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title_full_unstemmed catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title_short catena-Poly[[[(3,5-dimethyl-1H-pyrazole)­copper(II)]-μ-{N-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
title_sort catena-poly[[[(3,5-dimethyl-1h-pyrazole)­copper(ii)]-μ-{n-[1-(2-oxidophen­yl)ethyl­idene]-l-valinato}] methanol monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051769/
https://www.ncbi.nlm.nih.gov/pubmed/21522850
http://dx.doi.org/10.1107/S1600536811000304
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