Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)

In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl­amino)­pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate a...

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Detalles Bibliográficos
Autores principales: Benslimane, Meriem, Merazig, Hocine, Daran, Jean-Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051772/
https://www.ncbi.nlm.nih.gov/pubmed/21522891
http://dx.doi.org/10.1107/S1600536811002017
Descripción
Sumario:In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl­amino)­pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate anions, which are asymmetrically bonded in the equatorial plane. The complex and the crystal packing of the complex are stabilized by intra- and inter­molecular C—H⋯O hydrogen bonds, giving R (4) (2)(10) rings and generating a layer-like structure.

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