Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)

In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl­amino)­pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate a...

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Detalles Bibliográficos
Autores principales: Benslimane, Meriem, Merazig, Hocine, Daran, Jean-Claude
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051772/
https://www.ncbi.nlm.nih.gov/pubmed/21522891
http://dx.doi.org/10.1107/S1600536811002017
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author Benslimane, Meriem
Merazig, Hocine
Daran, Jean-Claude
author_facet Benslimane, Meriem
Merazig, Hocine
Daran, Jean-Claude
author_sort Benslimane, Meriem
collection PubMed
description In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl­amino)­pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate anions, which are asymmetrically bonded in the equatorial plane. The complex and the crystal packing of the complex are stabilized by intra- and inter­molecular C—H⋯O hydrogen bonds, giving R (4) (2)(10) rings and generating a layer-like structure.
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spelling pubmed-30517722011-04-26 Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II) Benslimane, Meriem Merazig, Hocine Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Cu(CH(3)COO)(2)(C(7)H(10)N(2))(2)], the Cu(II) ion, located on a crystallographic inversion centre, is six coordinated by two N atoms of two 4-(dimethyl­amino)­pyridine (DMAP) ligands in apical positions and four O atoms from two symmetry-related opposite acetate anions, which are asymmetrically bonded in the equatorial plane. The complex and the crystal packing of the complex are stabilized by intra- and inter­molecular C—H⋯O hydrogen bonds, giving R (4) (2)(10) rings and generating a layer-like structure. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051772/ /pubmed/21522891 http://dx.doi.org/10.1107/S1600536811002017 Text en © Benslimane et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benslimane, Meriem
Merazig, Hocine
Daran, Jean-Claude
Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title_full Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title_fullStr Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title_full_unstemmed Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title_short Bis(acetato-κ(2) O,O′)bis­[4-(dimethyl­amino)­pyridine-κN]copper(II)
title_sort bis(acetato-κ(2) o,o′)bis­[4-(dimethyl­amino)­pyridine-κn]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051772/
https://www.ncbi.nlm.nih.gov/pubmed/21522891
http://dx.doi.org/10.1107/S1600536811002017
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AT merazighocine bisacetatok2oobis4dimethylaminopyridinekncopperii
AT daranjeanclaude bisacetatok2oobis4dimethylaminopyridinekncopperii

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