Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate

The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris­(2-hy­droxy­benzoyl­amino­eth­yl)amine = H(3)saltren], uncoordin­ated perchlorate anions and acetonitrile solvent mol­ecules. The calcium ion is six-coordinated and is bo...

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Detalles Bibliográficos
Autores principales: Kose, Muhammet, McKee, Vickie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051774/
https://www.ncbi.nlm.nih.gov/pubmed/21522833
http://dx.doi.org/10.1107/S1600536810053961
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author Kose, Muhammet
McKee, Vickie
author_facet Kose, Muhammet
McKee, Vickie
author_sort Kose, Muhammet
collection PubMed
description The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris­(2-hy­droxy­benzoyl­amino­eth­yl)amine = H(3)saltren], uncoordin­ated perchlorate anions and acetonitrile solvent mol­ecules. The calcium ion is six-coordinated and is bonded to all phen­oxy O atoms from both zwitterionic saltren mol­ecules. There are strong intra­molecular N—H⋯O hydrogen bonds. The cations are linked into chains via weak inter­molecular C—H⋯O hydrogen bonds and C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.306 (3) and 3.415 (3) Å].
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spelling pubmed-30517742011-04-26 Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate Kose, Muhammet McKee, Vickie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ca(C(27)H(30)N(4)O(3))(2)](ClO(4))(2)·2CH(3)CN, is composed of centrosymmetric (CaL(2))(2+) cations [L = tris­(2-hy­droxy­benzoyl­amino­eth­yl)amine = H(3)saltren], uncoordin­ated perchlorate anions and acetonitrile solvent mol­ecules. The calcium ion is six-coordinated and is bonded to all phen­oxy O atoms from both zwitterionic saltren mol­ecules. There are strong intra­molecular N—H⋯O hydrogen bonds. The cations are linked into chains via weak inter­molecular C—H⋯O hydrogen bonds and C—H⋯π and π–π stacking inter­actions [centroid–centroid distances = 3.306 (3) and 3.415 (3) Å]. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051774/ /pubmed/21522833 http://dx.doi.org/10.1107/S1600536810053961 Text en © Kose and McKee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kose, Muhammet
McKee, Vickie
Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title_full Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title_fullStr Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title_full_unstemmed Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title_short Bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) O,O′,O′′}calcium bis(perchlorate) acetonitrile disolvate
title_sort bis{tris[2-(2-oxidobenzylideneazaniumyl)ethyl]amine-κ(3) o,o′,o′′}calcium bis(perchlorate) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051774/
https://www.ncbi.nlm.nih.gov/pubmed/21522833
http://dx.doi.org/10.1107/S1600536810053961
work_keys_str_mv AT kosemuhammet bistris22oxidobenzylideneazaniumylethylaminek3ooocalciumbisperchlorateacetonitriledisolvate
AT mckeevickie bistris22oxidobenzylideneazaniumylethylaminek3ooocalciumbisperchlorateacetonitriledisolvate

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