Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]

The title coordination polymer, [CdBr(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from...

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Detalles Bibliográficos
Autores principales: Xu, Xiu-Zhi, Li, Zhu-Lai, Yan, Wen-Jin, Chi, Hui-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051776/
https://www.ncbi.nlm.nih.gov/pubmed/21522860
http://dx.doi.org/10.1107/S1600536811000535
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author Xu, Xiu-Zhi
Li, Zhu-Lai
Yan, Wen-Jin
Chi, Hui-Li
author_facet Xu, Xiu-Zhi
Li, Zhu-Lai
Yan, Wen-Jin
Chi, Hui-Li
author_sort Xu, Xiu-Zhi
collection PubMed
description The title coordination polymer, [CdBr(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr(2)N(4) octa­hedral arrangement. The bridging 1-(4-pyridyl­meth­yl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 4(4) sheet structure in the crystal.
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spelling pubmed-30517762011-04-26 Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium] Xu, Xiu-Zhi Li, Zhu-Lai Yan, Wen-Jin Chi, Hui-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, [CdBr(2)(C(8)H(8)N(4))(2)](n), arose from a layer-separated diffusion synthesis at room temperature. The title compound is isotypic with the I and Cl analogues. The Cd atom, located on an inversion center, is coordinated by two bromide ions and four N atoms (two from triazole rings and two from pyridyl rings) in a distorted trans-CdBr(2)N(4) octa­hedral arrangement. The bridging 1-(4-pyridyl­meth­yl)-1H-1,2,4-triazole ligands are twisted [dihedral angle between the triazole and pyridine rings = 72.56 (13)°], affording a two-dimensional 4(4) sheet structure in the crystal. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051776/ /pubmed/21522860 http://dx.doi.org/10.1107/S1600536811000535 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Xiu-Zhi
Li, Zhu-Lai
Yan, Wen-Jin
Chi, Hui-Li
Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title_full Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title_fullStr Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title_full_unstemmed Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title_short Poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1H-1,2,4-triazole-κ(2) N:N′]cadmium]
title_sort poly[dibromidobis[μ-1-(pyridin-4-ylmeth­yl)-1h-1,2,4-triazole-κ(2) n:n′]cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051776/
https://www.ncbi.nlm.nih.gov/pubmed/21522860
http://dx.doi.org/10.1107/S1600536811000535
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