Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)

The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol­ecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex...

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Detalles Bibliográficos
Autores principales: Meng, Qingfen, Chen, Yanmei, Li, Bing, Chen, Sanping, Gao, Shengli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051778/
https://www.ncbi.nlm.nih.gov/pubmed/21522885
http://dx.doi.org/10.1107/S1600536810054073
Descripción
Sumario:The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol­ecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex cations form layers through π–π stacking [interplanar distance = 3.481 (2) Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.

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