Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)

The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol­ecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex...

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Detalles Bibliográficos
Autores principales: Meng, Qingfen, Chen, Yanmei, Li, Bing, Chen, Sanping, Gao, Shengli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051778/
https://www.ncbi.nlm.nih.gov/pubmed/21522885
http://dx.doi.org/10.1107/S1600536810054073
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author Meng, Qingfen
Chen, Yanmei
Li, Bing
Chen, Sanping
Gao, Shengli
author_facet Meng, Qingfen
Chen, Yanmei
Li, Bing
Chen, Sanping
Gao, Shengli
author_sort Meng, Qingfen
collection PubMed
description The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol­ecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex cations form layers through π–π stacking [interplanar distance = 3.481 (2) Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.
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spelling pubmed-30517782011-04-26 Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II) Meng, Qingfen Chen, Yanmei Li, Bing Chen, Sanping Gao, Shengli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol­ecules and one chloride anion in a distorted trigonal–bipyramidal geometry. The Cu(II) complex cations form layers through π–π stacking [interplanar distance = 3.481 (2) Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051778/ /pubmed/21522885 http://dx.doi.org/10.1107/S1600536810054073 Text en © Meng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Qingfen
Chen, Yanmei
Li, Bing
Chen, Sanping
Gao, Shengli
Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title_full Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title_fullStr Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title_full_unstemmed Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title_short Chloridobis(1,10-phenanthroline-κ(2) N,N′)copper(I) dichloridocopper(II)
title_sort chloridobis(1,10-phenanthroline-κ(2) n,n′)copper(i) dichloridocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051778/
https://www.ncbi.nlm.nih.gov/pubmed/21522885
http://dx.doi.org/10.1107/S1600536810054073
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AT libing chloridobis110phenanthrolinek2nncopperidichloridocopperii
AT chensanping chloridobis110phenanthrolinek2nncopperidichloridocopperii
AT gaoshengli chloridobis110phenanthrolinek2nncopperidichloridocopperii

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