(E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide

The title compound, C(14)H(11)N(3)O(5), is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) Å. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link adjacent mol­ecules into layers parallel to (101). These layers are further connected into a three-dimensional network via...

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Detalles Bibliográficos
Autores principales: Mohd Lair, Nooraziah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051779/
https://www.ncbi.nlm.nih.gov/pubmed/21523120
http://dx.doi.org/10.1107/S1600536811002224
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author Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Mohd Lair, Nooraziah
collection PubMed
description The title compound, C(14)H(11)N(3)O(5), is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) Å. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link adjacent mol­ecules into layers parallel to (101). These layers are further connected into a three-dimensional network via C—H⋯O inter­actions. In addition, a π–π inter­action occurs between the aromatic rings [centroid–centroid distance = 3.5425 (8) Å]. An intra­molecular O—H⋯N hydrogen bond is also observed.
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spelling pubmed-30517792011-04-26 (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide Mohd Lair, Nooraziah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)N(3)O(5), is essentially planar, with an r.m.s. deviation for the non-H atoms of 0.0832 (3) Å. In the crystal, O—H⋯O and N—H⋯O hydrogen bonds link adjacent mol­ecules into layers parallel to (101). These layers are further connected into a three-dimensional network via C—H⋯O inter­actions. In addition, a π–π inter­action occurs between the aromatic rings [centroid–centroid distance = 3.5425 (8) Å]. An intra­molecular O—H⋯N hydrogen bond is also observed. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051779/ /pubmed/21523120 http://dx.doi.org/10.1107/S1600536811002224 Text en © Mohd Lair et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohd Lair, Nooraziah
Khaledi, Hamid
Mohd Ali, Hapipah
(E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title_full (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title_fullStr (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title_full_unstemmed (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title_short (E)-N′-(2,4-Dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
title_sort (e)-n′-(2,4-dihy­droxy­benzyl­idene)-4-nitro­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051779/
https://www.ncbi.nlm.nih.gov/pubmed/21523120
http://dx.doi.org/10.1107/S1600536811002224
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