(Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide

The crystal structure of the title compound, C(22)H(18)BrN(3)O, is stabilized by π–π contacts [centroid–centroid distance = 3.476 (2) Å] between five-membered rings as well as inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. An intra­molecular N—H⋯O hydrogen bond occurs. The benzene rings make a dihe...

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Autores principales: Asgri, Davood, Ghanbari, Mohammad, Mehrdad, Morteza, Jadidi, Khosrow, Khavasi, Hamid Reza
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051780/
https://www.ncbi.nlm.nih.gov/pubmed/21523031
http://dx.doi.org/10.1107/S1600536811000833
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author Asgri, Davood
Ghanbari, Mohammad
Mehrdad, Morteza
Jadidi, Khosrow
Khavasi, Hamid Reza
author_facet Asgri, Davood
Ghanbari, Mohammad
Mehrdad, Morteza
Jadidi, Khosrow
Khavasi, Hamid Reza
author_sort Asgri, Davood
collection PubMed
description The crystal structure of the title compound, C(22)H(18)BrN(3)O, is stabilized by π–π contacts [centroid–centroid distance = 3.476 (2) Å] between five-membered rings as well as inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. An intra­molecular N—H⋯O hydrogen bond occurs. The benzene rings make a dihedral angle of 59.89 (8)°. The dihedral angles between the fused ring systemand the two benzene rings are 3.46 (7) and 61.97 (7)°.
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spelling pubmed-30517802011-04-26 (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide Asgri, Davood Ghanbari, Mohammad Mehrdad, Morteza Jadidi, Khosrow Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title compound, C(22)H(18)BrN(3)O, is stabilized by π–π contacts [centroid–centroid distance = 3.476 (2) Å] between five-membered rings as well as inter­molecular C—H⋯O and C—H⋯N hydrogen bonds. An intra­molecular N—H⋯O hydrogen bond occurs. The benzene rings make a dihedral angle of 59.89 (8)°. The dihedral angles between the fused ring systemand the two benzene rings are 3.46 (7) and 61.97 (7)°. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051780/ /pubmed/21523031 http://dx.doi.org/10.1107/S1600536811000833 Text en © Asgri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asgri, Davood
Ghanbari, Mohammad
Mehrdad, Morteza
Jadidi, Khosrow
Khavasi, Hamid Reza
(Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title_full (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title_fullStr (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title_full_unstemmed (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title_short (Z)-N-[5-Bromo-2-(4-methyl­anilino)-3H-indol-3-yl­idene]-4-methyl­aniline oxide
title_sort (z)-n-[5-bromo-2-(4-methyl­anilino)-3h-indol-3-yl­idene]-4-methyl­aniline oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051780/
https://www.ncbi.nlm.nih.gov/pubmed/21523031
http://dx.doi.org/10.1107/S1600536811000833
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