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4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)

The title compound, C(9)H(14)N(+)·I(3) (−)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl­pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I—I) and a bond angle of 177.55 (3)° (I—I—I). For this room-temperature str...

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Detalles Bibliográficos
Autores principales: He, Hongshan, Sykes, Andrew G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051785/
https://www.ncbi.nlm.nih.gov/pubmed/21523100
http://dx.doi.org/10.1107/S1600536811001371
Descripción
Sumario:The title compound, C(9)H(14)N(+)·I(3) (−)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl­pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I—I) and a bond angle of 177.55 (3)° (I—I—I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeric forms by way of N—H⋯N hydrogen bonds.