4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)

The title compound, C(9)H(14)N(+)·I(3) (−)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl­pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I—I) and a bond angle of 177.55 (3)° (I—I—I). For this room-temperature str...

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Detalles Bibliográficos
Autores principales: He, Hongshan, Sykes, Andrew G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051785/
https://www.ncbi.nlm.nih.gov/pubmed/21523100
http://dx.doi.org/10.1107/S1600536811001371
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author He, Hongshan
Sykes, Andrew G.
author_facet He, Hongshan
Sykes, Andrew G.
author_sort He, Hongshan
collection PubMed
description The title compound, C(9)H(14)N(+)·I(3) (−)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl­pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I—I) and a bond angle of 177.55 (3)° (I—I—I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeric forms by way of N—H⋯N hydrogen bonds.
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spelling pubmed-30517852011-04-26 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1) He, Hongshan Sykes, Andrew G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(14)N(+)·I(3) (−)·C(9)H(13)N, consists of monoprotonated 4-tert-butyl­pyridinium cations and triiodide anions. The triiodide ion has near-symmetric linear geometry, with bond lengths of 2.9105 (4) Å (I—I) and a bond angle of 177.55 (3)° (I—I—I). For this room-temperature structure, the butyl group on the pyridine ring is disordered and has been treated as a rigid rotator, modeled in three separate positions with 1/3, 1/3, 1/3 occupancies. The cations assemble into dimeric forms by way of N—H⋯N hydrogen bonds. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051785/ /pubmed/21523100 http://dx.doi.org/10.1107/S1600536811001371 Text en © He and Sykes 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Hongshan
Sykes, Andrew G.
4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title_full 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title_fullStr 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title_full_unstemmed 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title_short 4-tert-Butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
title_sort 4-tert-butyl­pyridinium triiodide–4-tert-butyl­pyridine (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051785/
https://www.ncbi.nlm.nih.gov/pubmed/21523100
http://dx.doi.org/10.1107/S1600536811001371
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AT sykesandrewg 4tertbutylpyridiniumtriiodide4tertbutylpyridine11

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