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(E)-Benzaldehyde (2,4,6-trichlorophenyl)hydrazone
The title compound, C(13)H(9)Cl(3)N(2), was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichlorophenylhydrazine. The molecule assumes an E configuration with the phenyl ring and trichlorophenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051786/ https://www.ncbi.nlm.nih.gov/pubmed/21523176 http://dx.doi.org/10.1107/S160053681100328X |
Sumario: | The title compound, C(13)H(9)Cl(3)N(2), was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichlorophenylhydrazine. The molecule assumes an E configuration with the phenyl ring and trichlorophenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral angle of 42.58 (12)° with respect to the tricholorophenyl ring. In the crystal, the molecules are linked via N—H⋯N hydrogen bonds, forming supramolecular chains running along the c axis. π–π stacking is present between parallel trichlorophenyl rings of adjacent molecules, the face-to-face and centroid–centroid distances being 3.369 (14) and 3.724 (2) Å, respectively. |
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