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(E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone

The title compound, C(13)H(9)Cl(3)N(2), was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichloro­phenyl­hydrazine. The mol­ecule assumes an E configuration with the phenyl ring and trichloro­phenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a...

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Autores principales: Huang, Yan-Lan, Li, Deng-Feng, Sun, Jian, Gao, Jin-Hua, Shan, Shang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051786/
https://www.ncbi.nlm.nih.gov/pubmed/21523176
http://dx.doi.org/10.1107/S160053681100328X
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author Huang, Yan-Lan
Li, Deng-Feng
Sun, Jian
Gao, Jin-Hua
Shan, Shang
author_facet Huang, Yan-Lan
Li, Deng-Feng
Sun, Jian
Gao, Jin-Hua
Shan, Shang
author_sort Huang, Yan-Lan
collection PubMed
description The title compound, C(13)H(9)Cl(3)N(2), was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichloro­phenyl­hydrazine. The mol­ecule assumes an E configuration with the phenyl ring and trichloro­phenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral angle of 42.58 (12)° with respect to the tricholorophenyl ring. In the crystal, the mol­ecules are linked via N—H⋯N hydrogen bonds, forming supra­molecular chains running along the c axis. π–π stacking is present between parallel trichloro­phenyl rings of adjacent mol­ecules, the face-to-face and centroid–centroid distances being 3.369 (14) and 3.724 (2) Å, respectively.
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spelling pubmed-30517862011-04-26 (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone Huang, Yan-Lan Li, Deng-Feng Sun, Jian Gao, Jin-Hua Shan, Shang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(9)Cl(3)N(2), was obtained from a condensation reaction of benzaldehyde and 2,4,6-trichloro­phenyl­hydrazine. The mol­ecule assumes an E configuration with the phenyl ring and trichloro­phenyl ring located on opposite sides of the C=N bond. The phenyl ring is oriented at a dihedral angle of 42.58 (12)° with respect to the tricholorophenyl ring. In the crystal, the mol­ecules are linked via N—H⋯N hydrogen bonds, forming supra­molecular chains running along the c axis. π–π stacking is present between parallel trichloro­phenyl rings of adjacent mol­ecules, the face-to-face and centroid–centroid distances being 3.369 (14) and 3.724 (2) Å, respectively. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051786/ /pubmed/21523176 http://dx.doi.org/10.1107/S160053681100328X Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Yan-Lan
Li, Deng-Feng
Sun, Jian
Gao, Jin-Hua
Shan, Shang
(E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title_full (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title_fullStr (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title_full_unstemmed (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title_short (E)-Benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
title_sort (e)-benzaldehyde (2,4,6-trichloro­phen­yl)hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051786/
https://www.ncbi.nlm.nih.gov/pubmed/21523176
http://dx.doi.org/10.1107/S160053681100328X
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AT shanshang ebenzaldehyde246trichlorophenylhydrazone