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{2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II)
The asymmetric unit of the title compound, [Zn(NCS)(2)(C(13)H(19)N(3)O)], contains two crystallographically independent molecules. In each molecule, the Zn(II) ion is five-coordinated by the N,N′,N"-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyram...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051787/ https://www.ncbi.nlm.nih.gov/pubmed/21522819 http://dx.doi.org/10.1107/S1600536810053778 |
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| author | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Suleiman Gwaram, Nura |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Zn(NCS)(2)(C(13)H(19)N(3)O)], contains two crystallographically independent molecules. In each molecule, the Zn(II) ion is five-coordinated by the N,N′,N"-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyramidal geometry. The two molecules differ mainly in the deviations from the ideal geometry, with τ values of 0.14 and 0.33. In the crystal, intermolecular C—H⋯S hydrogen bonds are observed. An intramolecular C—H⋯N hydrogen bond occurs in one of the independent molecules. |
| format | Text |
| id | pubmed-3051787 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30517872011-04-26 {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II) Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(NCS)(2)(C(13)H(19)N(3)O)], contains two crystallographically independent molecules. In each molecule, the Zn(II) ion is five-coordinated by the N,N′,N"-tridentate Schiff base and the N atoms of two thiocyanate ligands in a distorted square-pyramidal geometry. The two molecules differ mainly in the deviations from the ideal geometry, with τ values of 0.14 and 0.33. In the crystal, intermolecular C—H⋯S hydrogen bonds are observed. An intramolecular C—H⋯N hydrogen bond occurs in one of the independent molecules. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051787/ /pubmed/21522819 http://dx.doi.org/10.1107/S1600536810053778 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_fullStr | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_full_unstemmed | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_short | {2-Morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
N,N′,N′′}bis(thiocyanato-κN)zinc(II) |
| title_sort | {2-morpholino-n-[1-(2-pyridyl)ethylidene]ethanamine-κ(3)
n,n′,n′′}bis(thiocyanato-κn)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051787/ https://www.ncbi.nlm.nih.gov/pubmed/21522819 http://dx.doi.org/10.1107/S1600536810053778 |
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