Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate

In the title complex, [Cu(C(7)H(4)NO(4))(2)]·2C(2)H(6)OS, the Cu(II) atom is situated on an inversion centre and is N,O-chelated by two monoanionic 4-carb­oxy­pyridine-2-carboxyl­ate ligands in a slightly distorted square-planar coordination geometry. The dimethyl sulfoxide solvent mol­ecules and Cu...

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Detalles Bibliográficos
Autores principales: Aghabozorg, Hossein, Goodarzi, Saba, Mirzaei, Masoud, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051791/
https://www.ncbi.nlm.nih.gov/pubmed/21522932
http://dx.doi.org/10.1107/S1600536811003424
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author Aghabozorg, Hossein
Goodarzi, Saba
Mirzaei, Masoud
Notash, Behrouz
author_facet Aghabozorg, Hossein
Goodarzi, Saba
Mirzaei, Masoud
Notash, Behrouz
author_sort Aghabozorg, Hossein
collection PubMed
description In the title complex, [Cu(C(7)H(4)NO(4))(2)]·2C(2)H(6)OS, the Cu(II) atom is situated on an inversion centre and is N,O-chelated by two monoanionic 4-carb­oxy­pyridine-2-carboxyl­ate ligands in a slightly distorted square-planar coordination geometry. The dimethyl sulfoxide solvent mol­ecules and Cu(II) complex mol­ecules are linked by O—H⋯O hydrogen bonding. In addition, C—H⋯O contacts and π–π inter­actions [centroid–centroid distance = 3.590 (1) Å] occur.
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spelling pubmed-30517912011-04-26 Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate Aghabozorg, Hossein Goodarzi, Saba Mirzaei, Masoud Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(4)NO(4))(2)]·2C(2)H(6)OS, the Cu(II) atom is situated on an inversion centre and is N,O-chelated by two monoanionic 4-carb­oxy­pyridine-2-carboxyl­ate ligands in a slightly distorted square-planar coordination geometry. The dimethyl sulfoxide solvent mol­ecules and Cu(II) complex mol­ecules are linked by O—H⋯O hydrogen bonding. In addition, C—H⋯O contacts and π–π inter­actions [centroid–centroid distance = 3.590 (1) Å] occur. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051791/ /pubmed/21522932 http://dx.doi.org/10.1107/S1600536811003424 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Aghabozorg, Hossein
Goodarzi, Saba
Mirzaei, Masoud
Notash, Behrouz
Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title_full Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title_fullStr Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title_full_unstemmed Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title_short Bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) N,O (2))copper(II) dimethyl sulfoxide disolvate
title_sort bis(4-carb­oxy­pyridine-2-carboxyl­ato-κ(2) n,o (2))copper(ii) dimethyl sulfoxide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051791/
https://www.ncbi.nlm.nih.gov/pubmed/21522932
http://dx.doi.org/10.1107/S1600536811003424
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AT notashbehrouz bis4carboxypyridine2carboxylatok2no2copperiidimethylsulfoxidedisolvate

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