Undeca­carbonyl-1κ(3) C,2κ(4) C,3κ(4) C-(triethyl phosphite-1κP)-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octa­hedral coord­ination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each o...

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Detalles Bibliográficos
Autores principales: Shawkataly, Omar bin, Alam, Mohd. Gulfam, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051793/
https://www.ncbi.nlm.nih.gov/pubmed/21522880
http://dx.doi.org/10.1107/S1600536811001450
Descripción
Sumario:In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octa­hedral coord­ination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each of the remaining two Ru atoms carries two equatorial and two axial carbonyl groups. In the crystal, mol­ecules are linked into an inversion dimer by a pair of inter­molecular C—H⋯O hydrogen bonds and the dimers are stacked along the b axis.

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