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Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-(triethyl phosphite-1κP)-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octahedral coordination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each o...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051793/ https://www.ncbi.nlm.nih.gov/pubmed/21522880 http://dx.doi.org/10.1107/S1600536811001450 |
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| author | Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun |
| author_facet | Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun |
| author_sort | Shawkataly, Omar bin |
| collection | PubMed |
| description | In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octahedral coordination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each of the remaining two Ru atoms carries two equatorial and two axial carbonyl groups. In the crystal, molecules are linked into an inversion dimer by a pair of intermolecular C—H⋯O hydrogen bonds and the dimers are stacked along the b axis. |
| format | Text |
| id | pubmed-3051793 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30517932011-04-26 Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octahedral coordination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each of the remaining two Ru atoms carries two equatorial and two axial carbonyl groups. In the crystal, molecules are linked into an inversion dimer by a pair of intermolecular C—H⋯O hydrogen bonds and the dimers are stacked along the b axis. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051793/ /pubmed/21522880 http://dx.doi.org/10.1107/S1600536811001450 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Alam, Mohd. Gulfam Yeap, Chin Sing Fun, Hoong-Kun Undecacarbonyl-1κ(3) C,2κ(4) C,3κ(4) C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title_full | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title_fullStr | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title_full_unstemmed | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title_short | Undecacarbonyl-1κ(3)
C,2κ(4)
C,3κ(4)
C-(triethyl phosphite-1κP)-triangulo-triruthenium(0) |
| title_sort | undecacarbonyl-1κ(3)
c,2κ(4)
c,3κ(4)
c-(triethyl phosphite-1κp)-triangulo-triruthenium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051793/ https://www.ncbi.nlm.nih.gov/pubmed/21522880 http://dx.doi.org/10.1107/S1600536811001450 |
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