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Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate

The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half-mol­ecule of the dichloro­methane solvent. The dichloro­methane solvent mol­ecule lies across a crystallograp...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Hafiz Malik, H. A., Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051800/
https://www.ncbi.nlm.nih.gov/pubmed/21522879
http://dx.doi.org/10.1107/S1600536811000778
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half-mol­ecule of the dichloro­methane solvent. The dichloro­methane solvent mol­ecule lies across a crystallographic inversion center leading to the mol­ecule being disordered over two positions of equal occupancy. The bis­(diphenyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. All phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 87.18 (11), 59.59 (10) and 89.28 (11)° with each other. The dihedral angles between the two benzene rings are 78.48 (11) and 87.58 (11)° for the two diphenyl­phosphanyl groups. In the crystal, the mol­ecules are stacked along the a axis. Weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure.
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spelling pubmed-30518002011-04-26 Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex mol­ecule and one half-mol­ecule of the dichloro­methane solvent. The dichloro­methane solvent mol­ecule lies across a crystallographic inversion center leading to the mol­ecule being disordered over two positions of equal occupancy. The bis­(diphenyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. All phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 87.18 (11), 59.59 (10) and 89.28 (11)° with each other. The dihedral angles between the two benzene rings are 78.48 (11) and 87.58 (11)° for the two diphenyl­phosphanyl groups. In the crystal, the mol­ecules are stacked along the a axis. Weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051800/ /pubmed/21522879 http://dx.doi.org/10.1107/S1600536811000778 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title_full Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title_fullStr Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title_full_unstemmed Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title_short Bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
title_sort bis{[μ-bis­(diphenyl­phosphan­yl)methane-1:2κ(2) p:p′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κp]-triangulo-triruthen­ium(0)} dichloro­methane monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051800/
https://www.ncbi.nlm.nih.gov/pubmed/21522879
http://dx.doi.org/10.1107/S1600536811000778
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