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Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate
The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half-molecule of the dichloromethane solvent. The dichloromethane solvent molecule lies across a crystallograp...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051800/ https://www.ncbi.nlm.nih.gov/pubmed/21522879 http://dx.doi.org/10.1107/S1600536811000778 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half-molecule of the dichloromethane solvent. The dichloromethane solvent molecule lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. All phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 87.18 (11), 59.59 (10) and 89.28 (11)° with each other. The dihedral angles between the two benzene rings are 78.48 (11) and 87.58 (11)° for the two diphenylphosphanyl groups. In the crystal, the molecules are stacked along the a axis. Weak intermolecular C—H⋯π interactions stabilize the crystal structure. |
format | Text |
id | pubmed-3051800 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30518002011-04-26 Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, 2[Ru(3)(C(25)H(22)P(2))(C(19)H(17)PS)(CO)(9)]·CH(2)Cl(2), contains one triangulo-triruthenium complex molecule and one half-molecule of the dichloromethane solvent. The dichloromethane solvent molecule lies across a crystallographic inversion center leading to the molecule being disordered over two positions of equal occupancy. The bis(diphenylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. All phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 87.18 (11), 59.59 (10) and 89.28 (11)° with each other. The dihedral angles between the two benzene rings are 78.48 (11) and 87.58 (11)° for the two diphenylphosphanyl groups. In the crystal, the molecules are stacked along the a axis. Weak intermolecular C—H⋯π interactions stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051800/ /pubmed/21522879 http://dx.doi.org/10.1107/S1600536811000778 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title | Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title_full | Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title_fullStr | Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title_full_unstemmed | Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title_short | Bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)} dichloromethane monosolvate |
title_sort | bis{[μ-bis(diphenylphosphanyl)methane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[(4-methylsulfanylphenyl)diphenylphosphane-3κp]-triangulo-triruthenium(0)} dichloromethane monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051800/ https://www.ncbi.nlm.nih.gov/pubmed/21522879 http://dx.doi.org/10.1107/S1600536811000778 |
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