Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]

In the title compound, [Ni(NCS)(2)(CH(3)CN)(2)](n), the Ni(II) cation is coordinated by two N-bonded and two S-bonded thio­cyanate anions, as well as two acetonitrile mol­ecules in an octa­hedral NiN(4)S(2) coordination mode. The asymmetric unit comprises one nickel cation, two thio­cyanate anions a...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051924/
https://www.ncbi.nlm.nih.gov/pubmed/21522245
http://dx.doi.org/10.1107/S1600536811004132
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description In the title compound, [Ni(NCS)(2)(CH(3)CN)(2)](n), the Ni(II) cation is coordinated by two N-bonded and two S-bonded thio­cyanate anions, as well as two acetonitrile mol­ecules in an octa­hedral NiN(4)S(2) coordination mode. The asymmetric unit comprises one nickel cation, two thio­cyanate anions and two actonitrile mol­ecules. In the crystal, the Ni(II) cations are connected by bridging thio­cyanate anions into a three-dimensional coordination network.
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spelling pubmed-30519242011-04-26 Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(NCS)(2)(CH(3)CN)(2)](n), the Ni(II) cation is coordinated by two N-bonded and two S-bonded thio­cyanate anions, as well as two acetonitrile mol­ecules in an octa­hedral NiN(4)S(2) coordination mode. The asymmetric unit comprises one nickel cation, two thio­cyanate anions and two actonitrile mol­ecules. In the crystal, the Ni(II) cations are connected by bridging thio­cyanate anions into a three-dimensional coordination network. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3051924/ /pubmed/21522245 http://dx.doi.org/10.1107/S1600536811004132 Text en © Wöhlert et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title_full Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title_fullStr Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title_full_unstemmed Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title_short Poly[bis­(acetonitrile-κN)di-μ-thio­cyanato-κ(2) N,S;κ(2) S,N-nickel(II)]
title_sort poly[bis­(acetonitrile-κn)di-μ-thio­cyanato-κ(2) n,s;κ(2) s,n-nickel(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051924/
https://www.ncbi.nlm.nih.gov/pubmed/21522245
http://dx.doi.org/10.1107/S1600536811004132
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