Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate

In the title compound, [Cr(C(15)H(22)BN(6))Cl(2)(C(5)H(8)N(2))]·C(4)H(8)O, the Cr(III) atom is coordinated by three N atoms from the hydro­tris­(3,5-dimethyl­pyrazol-1-yl)borate (Tp*) ligand, one 3,5-dimethyl­pyrazole (Dmpy) N atom and two Cl atoms in a distorted octa­hedral coordination geometry. T...

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Detalles Bibliográficos
Autores principales: Yuan, Li-Li, Chen, Chen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051926/
https://www.ncbi.nlm.nih.gov/pubmed/21522278
http://dx.doi.org/10.1107/S1600536811005344
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author Yuan, Li-Li
Chen, Chen
author_facet Yuan, Li-Li
Chen, Chen
author_sort Yuan, Li-Li
collection PubMed
description In the title compound, [Cr(C(15)H(22)BN(6))Cl(2)(C(5)H(8)N(2))]·C(4)H(8)O, the Cr(III) atom is coordinated by three N atoms from the hydro­tris­(3,5-dimethyl­pyrazol-1-yl)borate (Tp*) ligand, one 3,5-dimethyl­pyrazole (Dmpy) N atom and two Cl atoms in a distorted octa­hedral coordination geometry. Two N atoms occupy the axial sites, and the two Cl atoms and other two N atoms from Tp* lie in the equatorial plane. In the crystal, the complex mol­ecules and tetra­hydro­furan solvent mol­ecules are connected via inter­molecular N—H⋯O and C—H⋯O inter­actions.
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spelling pubmed-30519262011-04-26 Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate Yuan, Li-Li Chen, Chen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(15)H(22)BN(6))Cl(2)(C(5)H(8)N(2))]·C(4)H(8)O, the Cr(III) atom is coordinated by three N atoms from the hydro­tris­(3,5-dimethyl­pyrazol-1-yl)borate (Tp*) ligand, one 3,5-dimethyl­pyrazole (Dmpy) N atom and two Cl atoms in a distorted octa­hedral coordination geometry. Two N atoms occupy the axial sites, and the two Cl atoms and other two N atoms from Tp* lie in the equatorial plane. In the crystal, the complex mol­ecules and tetra­hydro­furan solvent mol­ecules are connected via inter­molecular N—H⋯O and C—H⋯O inter­actions. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3051926/ /pubmed/21522278 http://dx.doi.org/10.1107/S1600536811005344 Text en © Yuan and Chen 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Li-Li
Chen, Chen
Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title_full Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title_fullStr Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title_full_unstemmed Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title_short Dichlorido(3,5-dimethyl-1H-pyrazole-κN (2))[hydro­tris­(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))borato]chromium(III) tetra­hydro­furan mono­solvate
title_sort dichlorido(3,5-dimethyl-1h-pyrazole-κn (2))[hydro­tris­(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))borato]chromium(iii) tetra­hydro­furan mono­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051926/
https://www.ncbi.nlm.nih.gov/pubmed/21522278
http://dx.doi.org/10.1107/S1600536811005344
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AT chenchen dichlorido35dimethyl1hpyrazolekn2hydrotris35dimethyl1hpyrazol1ylkn2boratochromiumiiitetrahydrofuranmonosolvate

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