9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one

The title compound, C(15)H(18)O(3), was isolated from Lacta­rius piperatus (Fr.) S. F. Gary collected from the Kunming area in Yunnan province, China. The central cyclo­hexyl ring adopts a chair conformation, while the furan­one ring is close to planar (r.m.s. deviation = 0.0174 Å). The remaining me...

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Detalles Bibliográficos
Autores principales: Liu, Wen-Hong, He, Jie, Ding, Zhi-Shan, Song, Zhong-Cheng, Zhan, Zha-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051927/
https://www.ncbi.nlm.nih.gov/pubmed/21522471
http://dx.doi.org/10.1107/S1600536811006519
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author Liu, Wen-Hong
He, Jie
Ding, Zhi-Shan
Song, Zhong-Cheng
Zhan, Zha-Jun
author_facet Liu, Wen-Hong
He, Jie
Ding, Zhi-Shan
Song, Zhong-Cheng
Zhan, Zha-Jun
author_sort Liu, Wen-Hong
collection PubMed
description The title compound, C(15)H(18)O(3), was isolated from Lacta­rius piperatus (Fr.) S. F. Gary collected from the Kunming area in Yunnan province, China. The central cyclo­hexyl ring adopts a chair conformation, while the furan­one ring is close to planar (r.m.s. deviation = 0.0174 Å). The remaining methyl­ene cyclo­hexene ring has a flattened chair conformation. In the crystal, mol­ecules are linked via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds into zigzag chains along the a axis.
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spelling pubmed-30519272011-04-26 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one Liu, Wen-Hong He, Jie Ding, Zhi-Shan Song, Zhong-Cheng Zhan, Zha-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(18)O(3), was isolated from Lacta­rius piperatus (Fr.) S. F. Gary collected from the Kunming area in Yunnan province, China. The central cyclo­hexyl ring adopts a chair conformation, while the furan­one ring is close to planar (r.m.s. deviation = 0.0174 Å). The remaining methyl­ene cyclo­hexene ring has a flattened chair conformation. In the crystal, mol­ecules are linked via inter­molecular O—H⋯O and C—H⋯O hydrogen bonds into zigzag chains along the a axis. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051927/ /pubmed/21522471 http://dx.doi.org/10.1107/S1600536811006519 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Wen-Hong
He, Jie
Ding, Zhi-Shan
Song, Zhong-Cheng
Zhan, Zha-Jun
9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title_full 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title_fullStr 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title_full_unstemmed 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title_short 9a-Hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8aH)-one
title_sort 9a-hy­droxy-3,8a-dimethyl-5-methyl­ene-4,4a,5,6,9,9a-hexa­hydro­naphtho­[2,3-b]furan-2(8ah)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051927/
https://www.ncbi.nlm.nih.gov/pubmed/21522471
http://dx.doi.org/10.1107/S1600536811006519
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