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Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water molecule on a general position. Each Cd(II) cation is six-coordinated by th...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051929/ https://www.ncbi.nlm.nih.gov/pubmed/21522256 http://dx.doi.org/10.1107/S1600536811004727 |
Sumario: | The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water molecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand and three O atoms from two different 1,4-chdc(2−) ligands (1,4-H(2)chdc = cyclohexane-1,4-dicarboxylic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octahedral coordination sphere is completed by a coordinated water molecule. The Cd(II) atoms are each bridged by two 1,4-chdc(2−) ligands, forming an inversion dimer with the L ligands located on the outside of the dimeric unit. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding interactions stabilize the packing. |
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