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Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate

The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol­ecule on a general position. Each Cd(II) cation is six-coordinated by th...

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Detalles Bibliográficos
Autores principales: Wang, Xiu-Yan, Ma, Shuai, He, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051929/
https://www.ncbi.nlm.nih.gov/pubmed/21522256
http://dx.doi.org/10.1107/S1600536811004727
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author Wang, Xiu-Yan
Ma, Shuai
He, Yu
author_facet Wang, Xiu-Yan
Ma, Shuai
He, Yu
author_sort Wang, Xiu-Yan
collection PubMed
description The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol­ecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand and three O atoms from two different 1,4-chdc(2−) ligands (1,4-H(2)chdc = cyclo­hexane-1,4-dicarb­oxy­lic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octa­hedral coordination sphere is completed by a coordinated water mol­ecule. The Cd(II) atoms are each bridged by two 1,4-chdc(2−) ligands, forming an inversion dimer with the L ligands located on the outside of the dimeric unit. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding inter­actions stabilize the packing.
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spelling pubmed-30519292011-04-26 Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate Wang, Xiu-Yan Ma, Shuai He, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol­ecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand and three O atoms from two different 1,4-chdc(2−) ligands (1,4-H(2)chdc = cyclo­hexane-1,4-dicarb­oxy­lic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octa­hedral coordination sphere is completed by a coordinated water mol­ecule. The Cd(II) atoms are each bridged by two 1,4-chdc(2−) ligands, forming an inversion dimer with the L ligands located on the outside of the dimeric unit. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding inter­actions stabilize the packing. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051929/ /pubmed/21522256 http://dx.doi.org/10.1107/S1600536811004727 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xiu-Yan
Ma, Shuai
He, Yu
Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title_full Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title_fullStr Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title_full_unstemmed Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title_short Bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
title_sort bis(μ-cyclo­hexane-1,4-dicarboxyl­ato)bis­{aqua­[1-(1h-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051929/
https://www.ncbi.nlm.nih.gov/pubmed/21522256
http://dx.doi.org/10.1107/S1600536811004727
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