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Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water molecule on a general position. Each Cd(II) cation is six-coordinated by th...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051929/ https://www.ncbi.nlm.nih.gov/pubmed/21522256 http://dx.doi.org/10.1107/S1600536811004727 |
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author | Wang, Xiu-Yan Ma, Shuai He, Yu |
author_facet | Wang, Xiu-Yan Ma, Shuai He, Yu |
author_sort | Wang, Xiu-Yan |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water molecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand and three O atoms from two different 1,4-chdc(2−) ligands (1,4-H(2)chdc = cyclohexane-1,4-dicarboxylic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octahedral coordination sphere is completed by a coordinated water molecule. The Cd(II) atoms are each bridged by two 1,4-chdc(2−) ligands, forming an inversion dimer with the L ligands located on the outside of the dimeric unit. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding interactions stabilize the packing. |
format | Text |
id | pubmed-3051929 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519292011-04-26 Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate Wang, Xiu-Yan Ma, Shuai He, Yu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water molecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand and three O atoms from two different 1,4-chdc(2−) ligands (1,4-H(2)chdc = cyclohexane-1,4-dicarboxylic acid), two coordinating in a bidentate fashion and the other in a monodentate fashion. The distorted octahedral coordination sphere is completed by a coordinated water molecule. The Cd(II) atoms are each bridged by two 1,4-chdc(2−) ligands, forming an inversion dimer with the L ligands located on the outside of the dimeric unit. An intramolecular N—H⋯O hydrogen bond occurs. In the crystal, O—H⋯O and N—H⋯O hydrogen-bonding interactions stabilize the packing. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051929/ /pubmed/21522256 http://dx.doi.org/10.1107/S1600536811004727 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Xiu-Yan Ma, Shuai He, Yu Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title | Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title_full | Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title_fullStr | Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title_full_unstemmed | Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title_short | Bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
title_sort | bis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1h-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051929/ https://www.ncbi.nlm.nih.gov/pubmed/21522256 http://dx.doi.org/10.1107/S1600536811004727 |
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