2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate

Two formula units of the title compound, 2-H(3)N-closo-1-CB(11)H(11)·CH(3)CH(2)OH or CH(14)B(11)N·C(2)H(5)OH, form a ring motif of R (4) (2)(8) type in the solid state that surrounds a crystallographic center of symmetry. The ring motif is a result of N—H⋯O hydrogen bonds. In contrast to many struct...

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Detalles Bibliográficos
Autores principales: Himmelspach, Alexander, Reiss, Guido J., Finze, Maik
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051930/
https://www.ncbi.nlm.nih.gov/pubmed/21522448
http://dx.doi.org/10.1107/S1600536811006222
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author Himmelspach, Alexander
Reiss, Guido J.
Finze, Maik
author_facet Himmelspach, Alexander
Reiss, Guido J.
Finze, Maik
author_sort Himmelspach, Alexander
collection PubMed
description Two formula units of the title compound, 2-H(3)N-closo-1-CB(11)H(11)·CH(3)CH(2)OH or CH(14)B(11)N·C(2)H(5)OH, form a ring motif of R (4) (2)(8) type in the solid state that surrounds a crystallographic center of symmetry. The ring motif is a result of N—H⋯O hydrogen bonds. In contrast to many structures of {closo-1-CB(11)} clusters, the assignment of the position of the cluster C atom in the structure of the title compound is unambigious. The relatively long B—N bond length [1.5396 (10) Å] documents the absence of any B—N π-inter­action in the title compound although this was observed for a related 2-amino­carba-closo-dodeca­borate.
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spelling pubmed-30519302011-04-26 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate Himmelspach, Alexander Reiss, Guido J. Finze, Maik Acta Crystallogr Sect E Struct Rep Online Organic Papers Two formula units of the title compound, 2-H(3)N-closo-1-CB(11)H(11)·CH(3)CH(2)OH or CH(14)B(11)N·C(2)H(5)OH, form a ring motif of R (4) (2)(8) type in the solid state that surrounds a crystallographic center of symmetry. The ring motif is a result of N—H⋯O hydrogen bonds. In contrast to many structures of {closo-1-CB(11)} clusters, the assignment of the position of the cluster C atom in the structure of the title compound is unambigious. The relatively long B—N bond length [1.5396 (10) Å] documents the absence of any B—N π-inter­action in the title compound although this was observed for a related 2-amino­carba-closo-dodeca­borate. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051930/ /pubmed/21522448 http://dx.doi.org/10.1107/S1600536811006222 Text en © Himmelspach et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Himmelspach, Alexander
Reiss, Guido J.
Finze, Maik
2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title_full 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title_fullStr 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title_full_unstemmed 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title_short 2-Aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
title_sort 2-aza­niumylcarba-closo-dodeca­borate ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051930/
https://www.ncbi.nlm.nih.gov/pubmed/21522448
http://dx.doi.org/10.1107/S1600536811006222
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AT reissguidoj 2azaniumylcarbaclosododecaborateethanolmonosolvate
AT finzemaik 2azaniumylcarbaclosododecaborateethanolmonosolvate

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