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catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2):O (2′),N,O (6)-[(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2),N,O (6):O (6′)] pentahydrate]
The title compound, {(C(10)H(10)N(2))[Ce(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]·5H(2)O}(n), is composed of a one-dimensional anionic complex, a doubly protonated 4,4′-bipyridine molecule as a counter-ion and five uncoordinated water molecules. The anion bears two nine-coordinate Ce(III) ions, each with a...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051934/ https://www.ncbi.nlm.nih.gov/pubmed/21522266 http://dx.doi.org/10.1107/S1600536811004995 |
| _version_ | 1782199587199516672 |
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| author | Aghabozorg, Hossein Omidvar, Sara Mirzaei, Masoud Notash, Behrouz |
| author_facet | Aghabozorg, Hossein Omidvar, Sara Mirzaei, Masoud Notash, Behrouz |
| author_sort | Aghabozorg, Hossein |
| collection | PubMed |
| description | The title compound, {(C(10)H(10)N(2))[Ce(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]·5H(2)O}(n), is composed of a one-dimensional anionic complex, a doubly protonated 4,4′-bipyridine molecule as a counter-ion and five uncoordinated water molecules. The anion bears two nine-coordinate Ce(III) ions, each with a distorted tricapped trigonal–prismatic geometry. In the crystal, intermolecular C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds, as well as π–π interactions with centroid–centroid distances of 3.514 (3) Å connect the various components into a supramolecular structure. |
| format | Text |
| id | pubmed-3051934 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30519342011-04-26 catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2):O (2′),N,O (6)-[(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2),N,O (6):O (6′)] pentahydrate] Aghabozorg, Hossein Omidvar, Sara Mirzaei, Masoud Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {(C(10)H(10)N(2))[Ce(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]·5H(2)O}(n), is composed of a one-dimensional anionic complex, a doubly protonated 4,4′-bipyridine molecule as a counter-ion and five uncoordinated water molecules. The anion bears two nine-coordinate Ce(III) ions, each with a distorted tricapped trigonal–prismatic geometry. In the crystal, intermolecular C—H⋯O, N—H⋯O and O—H⋯O hydrogen bonds, as well as π–π interactions with centroid–centroid distances of 3.514 (3) Å connect the various components into a supramolecular structure. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051934/ /pubmed/21522266 http://dx.doi.org/10.1107/S1600536811004995 Text en © Aghabozorg et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Aghabozorg, Hossein Omidvar, Sara Mirzaei, Masoud Notash, Behrouz catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2):O (2′),N,O (6)-[(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4) O (2),N,O (6):O (6′)] pentahydrate] |
| title |
catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2):O
(2′),N,O
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2),N,O
(6):O
(6′)] pentahydrate] |
| title_full |
catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2):O
(2′),N,O
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2),N,O
(6):O
(6′)] pentahydrate] |
| title_fullStr |
catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2):O
(2′),N,O
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2),N,O
(6):O
(6′)] pentahydrate] |
| title_full_unstemmed |
catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2):O
(2′),N,O
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2),N,O
(6):O
(6′)] pentahydrate] |
| title_short |
catena-Poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2):O
(2′),N,O
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))cerate(III)]-μ-pyridine-2,6-dicarboxylato-κ(4)
O
(2),N,O
(6):O
(6′)] pentahydrate] |
| title_sort | catena-poly[4,4′-bipyridinium [[tetraaqua(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cerate(iii)]-μ-pyridine-2,6-dicarboxylato-κ(4)
o
(2):o
(2′),n,o
(6)-[(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))cerate(iii)]-μ-pyridine-2,6-dicarboxylato-κ(4)
o
(2),n,o
(6):o
(6′)] pentahydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051934/ https://www.ncbi.nlm.nih.gov/pubmed/21522266 http://dx.doi.org/10.1107/S1600536811004995 |
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