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[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′](methanol-κO)(nitrito-κ(2) O,O′)cadmium(II) perchlorate
In the title complex, [Cd(NO(2))(C(22)H(20)N(6))(CH(3)OH)]ClO(4), the Cd(II) ion is in a distorted pentagonal–bipyramidal CdN(4)O(3) coordination geometry. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline ring system are 4.37 (19) and 5.84 (21)°. In th...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051935/ https://www.ncbi.nlm.nih.gov/pubmed/21522261 http://dx.doi.org/10.1107/S1600536811003813 |
| _version_ | 1782199587436494848 |
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| author | Liu, Li Zhen Chi, Yan Hui Du, Hua Shi, Jing Min |
| author_facet | Liu, Li Zhen Chi, Yan Hui Du, Hua Shi, Jing Min |
| author_sort | Liu, Li Zhen |
| collection | PubMed |
| description | In the title complex, [Cd(NO(2))(C(22)H(20)N(6))(CH(3)OH)]ClO(4), the Cd(II) ion is in a distorted pentagonal–bipyramidal CdN(4)O(3) coordination geometry. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline ring system are 4.37 (19) and 5.84 (21)°. In the crystal, the anions and cations are connected by intermolecular O—H⋯O hydrogen bonding, while pairs of weak intermolecular C—H⋯O hydrogen bonds connect the cations into centrosymmetric dimers. In addition, there is a π–π stacking interaction involving two symmetry-related benzene rings, with a centroid–centroid distance of 3.437 (3) Å. |
| format | Text |
| id | pubmed-3051935 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30519352011-04-26 [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′](methanol-κO)(nitrito-κ(2) O,O′)cadmium(II) perchlorate Liu, Li Zhen Chi, Yan Hui Du, Hua Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(NO(2))(C(22)H(20)N(6))(CH(3)OH)]ClO(4), the Cd(II) ion is in a distorted pentagonal–bipyramidal CdN(4)O(3) coordination geometry. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline ring system are 4.37 (19) and 5.84 (21)°. In the crystal, the anions and cations are connected by intermolecular O—H⋯O hydrogen bonding, while pairs of weak intermolecular C—H⋯O hydrogen bonds connect the cations into centrosymmetric dimers. In addition, there is a π–π stacking interaction involving two symmetry-related benzene rings, with a centroid–centroid distance of 3.437 (3) Å. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051935/ /pubmed/21522261 http://dx.doi.org/10.1107/S1600536811003813 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Li Zhen Chi, Yan Hui Du, Hua Shi, Jing Min [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′](methanol-κO)(nitrito-κ(2) O,O′)cadmium(II) perchlorate |
| title | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′](methanol-κO)(nitrito-κ(2)
O,O′)cadmium(II) perchlorate |
| title_full | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′](methanol-κO)(nitrito-κ(2)
O,O′)cadmium(II) perchlorate |
| title_fullStr | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′](methanol-κO)(nitrito-κ(2)
O,O′)cadmium(II) perchlorate |
| title_full_unstemmed | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′](methanol-κO)(nitrito-κ(2)
O,O′)cadmium(II) perchlorate |
| title_short | [2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))-1,10-phenanthroline-κ(2)
N,N′](methanol-κO)(nitrito-κ(2)
O,O′)cadmium(II) perchlorate |
| title_sort | [2,9-bis(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))-1,10-phenanthroline-κ(2)
n,n′](methanol-κo)(nitrito-κ(2)
o,o′)cadmium(ii) perchlorate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051935/ https://www.ncbi.nlm.nih.gov/pubmed/21522261 http://dx.doi.org/10.1107/S1600536811003813 |
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