Cargando…
1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate)
In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water molecules in a slightly distorted octahedral geometry. The 1,4-diazoniabicyclo[2.2.2]octane cation is located about a twofold rotation axis. Intermolecular N...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051936/ https://www.ncbi.nlm.nih.gov/pubmed/21522273 http://dx.doi.org/10.1107/S1600536811005368 |
_version_ | 1782199587669278720 |
---|---|
author | Zheng, Wen-Ni |
author_facet | Zheng, Wen-Ni |
author_sort | Zheng, Wen-Ni |
collection | PubMed |
description | In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water molecules in a slightly distorted octahedral geometry. The 1,4-diazoniabicyclo[2.2.2]octane cation is located about a twofold rotation axis. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network. |
format | Text |
id | pubmed-3051936 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519362011-04-26 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) Zheng, Wen-Ni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water molecules in a slightly distorted octahedral geometry. The 1,4-diazoniabicyclo[2.2.2]octane cation is located about a twofold rotation axis. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3051936/ /pubmed/21522273 http://dx.doi.org/10.1107/S1600536811005368 Text en © Wen-Ni Zheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zheng, Wen-Ni 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title | 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title_full | 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title_fullStr | 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title_full_unstemmed | 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title_short | 1,4-Diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
title_sort | 1,4-diazoniabicyclo[2.2.2]octane hexaaquamagnesium bis(sulfate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051936/ https://www.ncbi.nlm.nih.gov/pubmed/21522273 http://dx.doi.org/10.1107/S1600536811005368 |
work_keys_str_mv | AT zhengwenni 14diazoniabicyclo222octanehexaaquamagnesiumbissulfate |