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1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)

In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water mol­ecules in a slightly distorted octa­hedral geometry. The 1,4-diazo­niabicyclo­[2.2.2]octane cation is located about a twofold rotation axis. Inter­molecular N...

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Autor principal: Zheng, Wen-Ni
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051936/
https://www.ncbi.nlm.nih.gov/pubmed/21522273
http://dx.doi.org/10.1107/S1600536811005368
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author Zheng, Wen-Ni
author_facet Zheng, Wen-Ni
author_sort Zheng, Wen-Ni
collection PubMed
description In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water mol­ecules in a slightly distorted octa­hedral geometry. The 1,4-diazo­niabicyclo­[2.2.2]octane cation is located about a twofold rotation axis. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network.
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spelling pubmed-30519362011-04-26 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate) Zheng, Wen-Ni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(14)N(2))[Mg(H(2)O)(6)](SO(4))(2), the Mg(II) ion, lying on an inversion center, is coordinated by six water mol­ecules in a slightly distorted octa­hedral geometry. The 1,4-diazo­niabicyclo­[2.2.2]octane cation is located about a twofold rotation axis. Inter­molecular N—H⋯O and O—H⋯O hydrogen bonds link the cations and the anions into a three-dimensional network. International Union of Crystallography 2011-02-19 /pmc/articles/PMC3051936/ /pubmed/21522273 http://dx.doi.org/10.1107/S1600536811005368 Text en © Wen-Ni Zheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Wen-Ni
1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane hexa­aqua­magnesium bis­(sulfate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051936/
https://www.ncbi.nlm.nih.gov/pubmed/21522273
http://dx.doi.org/10.1107/S1600536811005368
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