N-[(4-Carbamoylphen­yl)carbamothio­yl]-2,3,4,5-tetra­fluoro­benzamide

In the title compound, C(15)H(9)F(4)N(3)O(2)S, the N,N′-disubstituted thio­urea fragment adopts a cis,trans geometry, stabilized by an intra­molecular N—H⋯O hydrogen bond to the carbonyl O atom of the tetra­fluoro­benzoyl group. The central thio­urea group makes dihedral angles of 47.79 (7) and 35.54 (8)° with the two aromatic rings. In the crystal, mol­ecules are linked via N—H⋯O and N—H⋯S hydrogen bonds into two-dimensional polymeric structures parallel to (100). In turn, π–π stacking inter­actions between tetra­fluoro­benzene and benzene units [centroid–centroid distance = 3.996 (10) Å; dihedral angle = 13.60 (8)°] organize these two-dimensional assemblies into a three-dimensional framework.