1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine

There are two half-mol­ecules in the asymmetric unit of the title compound, C(32)H(30)Cl(4)N(4), in both of which the N—H bonds are syn to the meta-chloro substituents in the adjacent benzene ring. The other two Cl atoms of these two mol­ecules are disordered with occunpancy ratios of 0.79 (2):0.21 ...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Rodrigues, Vinola Z., Spandana, H. S., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051938/
https://www.ncbi.nlm.nih.gov/pubmed/21522366
http://dx.doi.org/10.1107/S1600536811004612
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author Gowda, B. Thimme
Foro, Sabine
Rodrigues, Vinola Z.
Spandana, H. S.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Rodrigues, Vinola Z.
Spandana, H. S.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description There are two half-mol­ecules in the asymmetric unit of the title compound, C(32)H(30)Cl(4)N(4), in both of which the N—H bonds are syn to the meta-chloro substituents in the adjacent benzene ring. The other two Cl atoms of these two mol­ecules are disordered with occunpancy ratios of 0.79 (2):0.21 (2) and 0.68 (1):0.32 (1). Adjacent chloro­phenyl rings make dihedral angles of 74.3 (2) and 63.0 (2)° in the two mol­ecules. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into infinite chains.
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spelling pubmed-30519382011-04-26 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine Gowda, B. Thimme Foro, Sabine Rodrigues, Vinola Z. Spandana, H. S. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two half-mol­ecules in the asymmetric unit of the title compound, C(32)H(30)Cl(4)N(4), in both of which the N—H bonds are syn to the meta-chloro substituents in the adjacent benzene ring. The other two Cl atoms of these two mol­ecules are disordered with occunpancy ratios of 0.79 (2):0.21 (2) and 0.68 (1):0.32 (1). Adjacent chloro­phenyl rings make dihedral angles of 74.3 (2) and 63.0 (2)° in the two mol­ecules. In the crystal, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into infinite chains. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051938/ /pubmed/21522366 http://dx.doi.org/10.1107/S1600536811004612 Text en © Gowda et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Rodrigues, Vinola Z.
Spandana, H. S.
Fuess, Hartmut
1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title_full 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title_fullStr 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title_full_unstemmed 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title_short 1,8-Bis(3-chloro­anilino)-N,N′-bis­(3-chloro­phen­yl)octane-1,8-diimine
title_sort 1,8-bis(3-chloro­anilino)-n,n′-bis­(3-chloro­phen­yl)octane-1,8-diimine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051938/
https://www.ncbi.nlm.nih.gov/pubmed/21522366
http://dx.doi.org/10.1107/S1600536811004612
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