Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate

In the title compound, C(7)H(14)NO(5)P, the phosphate group displays rotational disorder of three O atoms with an occupancy ratio of 0.832 (6):0.167 (6). The dihedral angle between the acryl­amide group and PO(2) plane of the phosphate group is 75.69 (7)°. In the crystal, inter­molecular N—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Cheon, Sanghun, Kim, Tae Ho, Park, Ki-Min, Kim, Jineun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051939/
https://www.ncbi.nlm.nih.gov/pubmed/21522345
http://dx.doi.org/10.1107/S1600536811003898
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author Cheon, Sanghun
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
author_facet Cheon, Sanghun
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
author_sort Cheon, Sanghun
collection PubMed
description In the title compound, C(7)H(14)NO(5)P, the phosphate group displays rotational disorder of three O atoms with an occupancy ratio of 0.832 (6):0.167 (6). The dihedral angle between the acryl­amide group and PO(2) plane of the phosphate group is 75.69 (7)°. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the molecules.
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spelling pubmed-30519392011-04-26 Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate Cheon, Sanghun Kim, Tae Ho Park, Ki-Min Kim, Jineun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(14)NO(5)P, the phosphate group displays rotational disorder of three O atoms with an occupancy ratio of 0.832 (6):0.167 (6). The dihedral angle between the acryl­amide group and PO(2) plane of the phosphate group is 75.69 (7)°. In the crystal, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the molecules. International Union of Crystallography 2011-02-09 /pmc/articles/PMC3051939/ /pubmed/21522345 http://dx.doi.org/10.1107/S1600536811003898 Text en © Cheon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheon, Sanghun
Kim, Tae Ho
Park, Ki-Min
Kim, Jineun
Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title_full Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title_fullStr Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title_full_unstemmed Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title_short Monocrotophos: dimethyl (E)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
title_sort monocrotophos: dimethyl (e)-1-methyl-2-(methyl­carbamo­yl)ethenyl phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051939/
https://www.ncbi.nlm.nih.gov/pubmed/21522345
http://dx.doi.org/10.1107/S1600536811003898
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AT kimtaeho monocrotophosdimethyle1methyl2methylcarbamoylethenylphosphate
AT parkkimin monocrotophosdimethyle1methyl2methylcarbamoylethenylphosphate
AT kimjineun monocrotophosdimethyle1methyl2methylcarbamoylethenylphosphate

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