1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate

In the title monohydrated salt, (C(6)H(14)N(2))[CuBr(4)]·H(2)O, the copper(II) ion is coordinated by the four bromide ions in a flattened tetra­hedral geometry. In the crystal, the cations, anions and water mol­ecules inter­act via N—H⋯O, O—H⋯Br and N—H⋯Br hydrogen bonds, forming chains parallel to...

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Detalles Bibliográficos
Autores principales: Zhang, Yi, Wang, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051942/
https://www.ncbi.nlm.nih.gov/pubmed/21522294
http://dx.doi.org/10.1107/S1600536811005289
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author Zhang, Yi
Wang, Bo
author_facet Zhang, Yi
Wang, Bo
author_sort Zhang, Yi
collection PubMed
description In the title monohydrated salt, (C(6)H(14)N(2))[CuBr(4)]·H(2)O, the copper(II) ion is coordinated by the four bromide ions in a flattened tetra­hedral geometry. In the crystal, the cations, anions and water mol­ecules inter­act via N—H⋯O, O—H⋯Br and N—H⋯Br hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by O—H⋯Br hydrogen bonds into layers parallel to the bc plane.
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spelling pubmed-30519422011-04-26 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate Zhang, Yi Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title monohydrated salt, (C(6)H(14)N(2))[CuBr(4)]·H(2)O, the copper(II) ion is coordinated by the four bromide ions in a flattened tetra­hedral geometry. In the crystal, the cations, anions and water mol­ecules inter­act via N—H⋯O, O—H⋯Br and N—H⋯Br hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by O—H⋯Br hydrogen bonds into layers parallel to the bc plane. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051942/ /pubmed/21522294 http://dx.doi.org/10.1107/S1600536811005289 Text en © Zhang and Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Yi
Wang, Bo
1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title_full 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title_fullStr 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title_full_unstemmed 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title_short 1,4-Diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(II) monohydrate
title_sort 1,4-diazo­niabicyclo­[2.2.2]octane tetra­bromidocuprate(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051942/
https://www.ncbi.nlm.nih.gov/pubmed/21522294
http://dx.doi.org/10.1107/S1600536811005289
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AT wangbo 14diazoniabicyclo222octanetetrabromidocuprateiimonohydrate

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