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2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one
The molecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hydroxy and methoxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051947/ https://www.ncbi.nlm.nih.gov/pubmed/21522458 http://dx.doi.org/10.1107/S1600536811006465 |
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author | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The molecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hydroxy and methoxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C = −177.96 (12)°]. An intramolecular O—H⋯N interaction generates an S(6) ring motif. In the crystal, molecules are linked by pairs of C—H⋯O interactions into dimers, which generate S(16) ring motifs. These dimers are arranged into sheets parallel to the ac plane and further stacked down the b axis by π–π interactions, with centroid–centroid distances in the range 3.5066 (8)–3.7241 (7) Å. |
format | Text |
id | pubmed-3051947 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519472011-04-26 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hydroxy and methoxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C = −177.96 (12)°]. An intramolecular O—H⋯N interaction generates an S(6) ring motif. In the crystal, molecules are linked by pairs of C—H⋯O interactions into dimers, which generate S(16) ring motifs. These dimers are arranged into sheets parallel to the ac plane and further stacked down the b axis by π–π interactions, with centroid–centroid distances in the range 3.5066 (8)–3.7241 (7) Å. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051947/ /pubmed/21522458 http://dx.doi.org/10.1107/S1600536811006465 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title | 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title_full | 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title_fullStr | 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title_full_unstemmed | 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title_short | 2-(2-Hydroxy-3-methoxyphenyl)-6H-perimidin-6-one |
title_sort | 2-(2-hydroxy-3-methoxyphenyl)-6h-perimidin-6-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051947/ https://www.ncbi.nlm.nih.gov/pubmed/21522458 http://dx.doi.org/10.1107/S1600536811006465 |
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