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2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one

The mol­ecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hy­droxy and meth­oxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051947/
https://www.ncbi.nlm.nih.gov/pubmed/21522458
http://dx.doi.org/10.1107/S1600536811006465
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author Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
author_facet Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hy­droxy and meth­oxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C = −177.96 (12)°]. An intra­molecular O—H⋯N inter­action generates an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of C—H⋯O inter­actions into dimers, which generate S(16) ring motifs. These dimers are arranged into sheets parallel to the ac plane and further stacked down the b axis by π–π inter­actions, with centroid–centroid distances in the range 3.5066 (8)–3.7241 (7) Å.
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spelling pubmed-30519472011-04-26 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one Fun, Hoong-Kun Chanawanno, Kullapa Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title perimidine derivative, C(18)H(12)N(2)O(3), is essentially planar, the dihedral angle between the benzene and perimidine rings being 3.25 (5)°. The hy­droxy and meth­oxy groups lie in the plane of the benzene ring to which they are bound [O—C—C—C = 179.96 (11)° and C—O—C—C = −177.96 (12)°]. An intra­molecular O—H⋯N inter­action generates an S(6) ring motif. In the crystal, mol­ecules are linked by pairs of C—H⋯O inter­actions into dimers, which generate S(16) ring motifs. These dimers are arranged into sheets parallel to the ac plane and further stacked down the b axis by π–π inter­actions, with centroid–centroid distances in the range 3.5066 (8)–3.7241 (7) Å. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051947/ /pubmed/21522458 http://dx.doi.org/10.1107/S1600536811006465 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chanawanno, Kullapa
Chantrapromma, Suchada
2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title_full 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title_fullStr 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title_full_unstemmed 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title_short 2-(2-Hy­droxy-3-meth­oxy­phen­yl)-6H-perimidin-6-one
title_sort 2-(2-hy­droxy-3-meth­oxy­phen­yl)-6h-perimidin-6-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051947/
https://www.ncbi.nlm.nih.gov/pubmed/21522458
http://dx.doi.org/10.1107/S1600536811006465
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