Cargando…

Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate

In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol­ecules are as...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Yu, Wu, Yun-Long, Huang, Chun-Xia, Xie, Ji-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051949/
https://www.ncbi.nlm.nih.gov/pubmed/21522243
http://dx.doi.org/10.1107/S1600536811002571
Descripción
Sumario:In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol­ecules are assembled by C—H⋯O hydrogen bonding and π–π inter­actions between bipy groups [centroid–centroid distances = 3.7686 (16) and 3.7002 (16) Å] into a three-dimensional network. The nitrite anion is equally disordered over two sets of sites.