Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate

In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol­ecules are as...

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Detalles Bibliográficos
Autores principales: Zhu, Yu, Wu, Yun-Long, Huang, Chun-Xia, Xie, Ji-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051949/
https://www.ncbi.nlm.nih.gov/pubmed/21522243
http://dx.doi.org/10.1107/S1600536811002571
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author Zhu, Yu
Wu, Yun-Long
Huang, Chun-Xia
Xie, Ji-Min
author_facet Zhu, Yu
Wu, Yun-Long
Huang, Chun-Xia
Xie, Ji-Min
author_sort Zhu, Yu
collection PubMed
description In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol­ecules are assembled by C—H⋯O hydrogen bonding and π–π inter­actions between bipy groups [centroid–centroid distances = 3.7686 (16) and 3.7002 (16) Å] into a three-dimensional network. The nitrite anion is equally disordered over two sets of sites.
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spelling pubmed-30519492011-04-26 Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate Zhu, Yu Wu, Yun-Long Huang, Chun-Xia Xie, Ji-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NO(3))(C(10)H(8)N(2))(2)]ClO(4), the five-coordinated Cu(II) atom has a distorted square-pyramidal CuN(4)O environment; the O atom is in the axial position whereas the N atoms from two bipyridine (bipy) ligands are in the equatorial plane. In the crystal, mol­ecules are assembled by C—H⋯O hydrogen bonding and π–π inter­actions between bipy groups [centroid–centroid distances = 3.7686 (16) and 3.7002 (16) Å] into a three-dimensional network. The nitrite anion is equally disordered over two sets of sites. International Union of Crystallography 2011-02-05 /pmc/articles/PMC3051949/ /pubmed/21522243 http://dx.doi.org/10.1107/S1600536811002571 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Yu
Wu, Yun-Long
Huang, Chun-Xia
Xie, Ji-Min
Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title_full Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title_fullStr Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title_full_unstemmed Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title_short Bis(2,2′-bipyridine-κ(2) N,N′)(nitrato-κO)copper(II) perchlorate
title_sort bis(2,2′-bipyridine-κ(2) n,n′)(nitrato-κo)copper(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051949/
https://www.ncbi.nlm.nih.gov/pubmed/21522243
http://dx.doi.org/10.1107/S1600536811002571
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AT huangchunxia bis22bipyridinek2nnnitratokocopperiiperchlorate
AT xiejimin bis22bipyridinek2nnnitratokocopperiiperchlorate

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