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Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate
In the title compound, [Pd(CH(3))(C(24)H(10)F(18)NOP)(CH(3)CN)][SbF(6)]·0.5CH(2)Cl(2), the Pd(II) atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd—N = 2.079 (3) Å], a methyl C atom [Pd—C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris(trifluoro...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051961/ https://www.ncbi.nlm.nih.gov/pubmed/21522290 http://dx.doi.org/10.1107/S1600536811005757 |
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author | Li, Liuzhong White, Peter S. Hao, Aiyou |
author_facet | Li, Liuzhong White, Peter S. Hao, Aiyou |
author_sort | Li, Liuzhong |
collection | PubMed |
description | In the title compound, [Pd(CH(3))(C(24)H(10)F(18)NOP)(CH(3)CN)][SbF(6)]·0.5CH(2)Cl(2), the Pd(II) atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd—N = 2.079 (3) Å], a methyl C atom [Pd—C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}methyl)pyridine (L). In L, the short distance of 3.621 (3) Å between the centroids of pyridine and benzene rings indicates the presence of a π–π interaction. The crystal packing exhibits weak intermolecular C—H⋯F contacts. The solvent molecule has been treated as disordered between two positions of equal occupancy related by an inversion center. |
format | Text |
id | pubmed-3051961 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519612011-04-26 Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate Li, Liuzhong White, Peter S. Hao, Aiyou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CH(3))(C(24)H(10)F(18)NOP)(CH(3)CN)][SbF(6)]·0.5CH(2)Cl(2), the Pd(II) atom has a distorted square-planar environment being coordinated by an acetonitrile N atom [Pd—N = 2.079 (3) Å], a methyl C atom [Pd—C = 2.047 (4) Å] and the bidentate ligand 2-({[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}methyl)pyridine (L). In L, the short distance of 3.621 (3) Å between the centroids of pyridine and benzene rings indicates the presence of a π–π interaction. The crystal packing exhibits weak intermolecular C—H⋯F contacts. The solvent molecule has been treated as disordered between two positions of equal occupancy related by an inversion center. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051961/ /pubmed/21522290 http://dx.doi.org/10.1107/S1600536811005757 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Liuzhong White, Peter S. Hao, Aiyou Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title | Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title_full | Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title_fullStr | Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title_full_unstemmed | Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title_short | Acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(II) hexafluoroantimonate dichloromethane hemisolvate |
title_sort | acetonitrile[2-({bis[2,4,6-tris(trifluoridomethyl)phenyl]phosphanyloxy}methyl)pyridine]methylpalladium(ii) hexafluoroantimonate dichloromethane hemisolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051961/ https://www.ncbi.nlm.nih.gov/pubmed/21522290 http://dx.doi.org/10.1107/S1600536811005757 |
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