5-Benzyl-7-methyl­hexa­hydro-3a,7-methano-1H-furo[3,4-c]azocine-3,10(4H)-dione

The title compound, C(18)H(21)NO(3), was obtained via a double Mannich condensation reaction of 6-methyl­tetra­hydro­isobenzofuran-1,7(3H,7aH)-dione with formaldehyde and benzyl­amine. The mol­ecule contains three fused rings of which the cyclo­hexa­none and piperidine rings adopt chair conformation...

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Detalles Bibliográficos
Autores principales: Yang, Zhan-Kun, Wang, Feng-Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051963/
https://www.ncbi.nlm.nih.gov/pubmed/21522339
http://dx.doi.org/10.1107/S160053681100300X
Descripción
Sumario:The title compound, C(18)H(21)NO(3), was obtained via a double Mannich condensation reaction of 6-methyl­tetra­hydro­isobenzofuran-1,7(3H,7aH)-dione with formaldehyde and benzyl­amine. The mol­ecule contains three fused rings of which the cyclo­hexa­none and piperidine rings adopt chair conformations and the furan­one ring assumes an envelope conformation. An inter­molecular C—H⋯π inter­action is present in the crystal structure.

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