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(E)-2-[4-(Diethyl­amino)­styr­yl]-1-methyl­pyridinium benzene­sulfonate mono­hydrate

The asymmetric unit of the title compound, C(18)H(23)N(2) (+)·C(6)H(5)O(3)S(−)·H(2)O, comprises a 2-[4-(diethyl­amino)­styr­yl]-1-methyl­pyridinium cation, a benzene­sulfonate anion and a solvent water mol­ecule. One ethyl substituent of the diethyl­amino group of the cation is disordered over two p...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Kaewmanee, Narissara, Chanawanno, Kullapa, Chantrapromma, Suchada
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051968/
https://www.ncbi.nlm.nih.gov/pubmed/21522353
http://dx.doi.org/10.1107/S1600536811004156
Descripción
Sumario:The asymmetric unit of the title compound, C(18)H(23)N(2) (+)·C(6)H(5)O(3)S(−)·H(2)O, comprises a 2-[4-(diethyl­amino)­styr­yl]-1-methyl­pyridinium cation, a benzene­sulfonate anion and a solvent water mol­ecule. One ethyl substituent of the diethyl­amino group of the cation is disordered over two positions in a 0.73789 (9):0.26211 (9) ratio. The cation exists in the E configuration with respect to the C=C bond and the π-conjugated system is essentially planar with a dihedral angle of 0.82 (10)° between the pyridinium and benzene rings. The cation and anion are almost orthogonal with a dihedral angle of 86.71 (10)° between the π-conjugated system of the cation and benzene ring of the anion. In the crystal, mol­ecules are arranged into chains along [001] and adjacent chains are linked by weak C—H⋯O inter­actions. The crystal is further stablilized by O—H⋯O hydrogen bonds and weak C—H⋯π inter­actions.