1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole

The title compound, C(17)H(18)N(2)O(2)S, was synthesized by aryl­sulfonyl­ation of 1-hy­droxy­methyl-1H-benzimidazole in the presence of triethyl­amine. The benzimidazole and benzene rings form a dihedral angle of 84.1 (1)°. The tert-butyl group was treated as rotationally disordered over two orient...

Descripción completa

Detalles Bibliográficos
Autores principales: Abdireymov, K. B., Mukhamedov, N. S., Okmanov, R. Ya., Ayimbetov, M. J., Shakhidoyatov, Kh. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051969/
https://www.ncbi.nlm.nih.gov/pubmed/21522452
http://dx.doi.org/10.1107/S1600536811005551
Descripción
Sumario:The title compound, C(17)H(18)N(2)O(2)S, was synthesized by aryl­sulfonyl­ation of 1-hy­droxy­methyl-1H-benzimidazole in the presence of triethyl­amine. The benzimidazole and benzene rings form a dihedral angle of 84.1 (1)°. The tert-butyl group was treated as rotationally disordered over two orientations in a 0.51 (2):0.49 (2) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains propagating in [010].

Ejemplares similares