1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole

The title compound, C(17)H(18)N(2)O(2)S, was synthesized by aryl­sulfonyl­ation of 1-hy­droxy­methyl-1H-benzimidazole in the presence of triethyl­amine. The benzimidazole and benzene rings form a dihedral angle of 84.1 (1)°. The tert-butyl group was treated as rotationally disordered over two orient...

Descripción completa

Detalles Bibliográficos
Autores principales: Abdireymov, K. B., Mukhamedov, N. S., Okmanov, R. Ya., Ayimbetov, M. J., Shakhidoyatov, Kh. M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051969/
https://www.ncbi.nlm.nih.gov/pubmed/21522452
http://dx.doi.org/10.1107/S1600536811005551
_version_ 1782199595539890176
author Abdireymov, K. B.
Mukhamedov, N. S.
Okmanov, R. Ya.
Ayimbetov, M. J.
Shakhidoyatov, Kh. M.
author_facet Abdireymov, K. B.
Mukhamedov, N. S.
Okmanov, R. Ya.
Ayimbetov, M. J.
Shakhidoyatov, Kh. M.
author_sort Abdireymov, K. B.
collection PubMed
description The title compound, C(17)H(18)N(2)O(2)S, was synthesized by aryl­sulfonyl­ation of 1-hy­droxy­methyl-1H-benzimidazole in the presence of triethyl­amine. The benzimidazole and benzene rings form a dihedral angle of 84.1 (1)°. The tert-butyl group was treated as rotationally disordered over two orientations in a 0.51 (2):0.49 (2) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains propagating in [010].
format Text
id pubmed-3051969
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30519692011-04-26 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole Abdireymov, K. B. Mukhamedov, N. S. Okmanov, R. Ya. Ayimbetov, M. J. Shakhidoyatov, Kh. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(18)N(2)O(2)S, was synthesized by aryl­sulfonyl­ation of 1-hy­droxy­methyl-1H-benzimidazole in the presence of triethyl­amine. The benzimidazole and benzene rings form a dihedral angle of 84.1 (1)°. The tert-butyl group was treated as rotationally disordered over two orientations in a 0.51 (2):0.49 (2) ratio. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains propagating in [010]. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051969/ /pubmed/21522452 http://dx.doi.org/10.1107/S1600536811005551 Text en © Abdireymov et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdireymov, K. B.
Mukhamedov, N. S.
Okmanov, R. Ya.
Ayimbetov, M. J.
Shakhidoyatov, Kh. M.
1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title_full 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title_fullStr 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title_full_unstemmed 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title_short 1-[(4-tert-Butyl­phen­yl)sulfon­yl]-1H-benzimidazole
title_sort 1-[(4-tert-butyl­phen­yl)sulfon­yl]-1h-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051969/
https://www.ncbi.nlm.nih.gov/pubmed/21522452
http://dx.doi.org/10.1107/S1600536811005551
work_keys_str_mv AT abdireymovkb 14tertbutylphenylsulfonyl1hbenzimidazole
AT mukhamedovns 14tertbutylphenylsulfonyl1hbenzimidazole
AT okmanovrya 14tertbutylphenylsulfonyl1hbenzimidazole
AT ayimbetovmj 14tertbutylphenylsulfonyl1hbenzimidazole
AT shakhidoyatovkhm 14tertbutylphenylsulfonyl1hbenzimidazole

Ejemplares similares