Bis(cytosinium) aqua­penta­chlorido­indate(III)

The asymmetric unit of the title compound, (C(4)H(6)N(3)O)(2)[InCl(5)(H(2)O)], comprises two independent cytosinium cations and an aquapentachloridoindate anion. The In(III) ion is in a slightly distorted octa­hedral coordination geometry. In the crystal, alternating layers of cations and anions are...

Descripción completa

Detalles Bibliográficos
Autores principales: Bouacida, Sofiane, Belhouas, Ratiba, Fantazi, Boubakeur, Boudaren, Chaouki, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051970/
https://www.ncbi.nlm.nih.gov/pubmed/21522251
http://dx.doi.org/10.1107/S1600536811004235
Descripción
Sumario:The asymmetric unit of the title compound, (C(4)H(6)N(3)O)(2)[InCl(5)(H(2)O)], comprises two independent cytosinium cations and an aquapentachloridoindate anion. The In(III) ion is in a slightly distorted octa­hedral coordination geometry. In the crystal, alternating layers of cations and anions are arranged along [010] and are linked via inter­molecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming sheets parallel to (001). Additional stabilization within these sheeets is provided by weak inter­molecular C—H⋯O inter­actions.

Ejemplares similares