Bis(cytosinium) aqua­penta­chlorido­indate(III)

The asymmetric unit of the title compound, (C(4)H(6)N(3)O)(2)[InCl(5)(H(2)O)], comprises two independent cytosinium cations and an aquapentachloridoindate anion. The In(III) ion is in a slightly distorted octa­hedral coordination geometry. In the crystal, alternating layers of cations and anions are...

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Autores principales: Bouacida, Sofiane, Belhouas, Ratiba, Fantazi, Boubakeur, Boudaren, Chaouki, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051970/
https://www.ncbi.nlm.nih.gov/pubmed/21522251
http://dx.doi.org/10.1107/S1600536811004235
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author Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
author_facet Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
author_sort Bouacida, Sofiane
collection PubMed
description The asymmetric unit of the title compound, (C(4)H(6)N(3)O)(2)[InCl(5)(H(2)O)], comprises two independent cytosinium cations and an aquapentachloridoindate anion. The In(III) ion is in a slightly distorted octa­hedral coordination geometry. In the crystal, alternating layers of cations and anions are arranged along [010] and are linked via inter­molecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming sheets parallel to (001). Additional stabilization within these sheeets is provided by weak inter­molecular C—H⋯O inter­actions.
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spelling pubmed-30519702011-04-26 Bis(cytosinium) aqua­penta­chlorido­indate(III) Bouacida, Sofiane Belhouas, Ratiba Fantazi, Boubakeur Boudaren, Chaouki Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(4)H(6)N(3)O)(2)[InCl(5)(H(2)O)], comprises two independent cytosinium cations and an aquapentachloridoindate anion. The In(III) ion is in a slightly distorted octa­hedral coordination geometry. In the crystal, alternating layers of cations and anions are arranged along [010] and are linked via inter­molecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds, forming sheets parallel to (001). Additional stabilization within these sheeets is provided by weak inter­molecular C—H⋯O inter­actions. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051970/ /pubmed/21522251 http://dx.doi.org/10.1107/S1600536811004235 Text en © Bouacida et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouacida, Sofiane
Belhouas, Ratiba
Fantazi, Boubakeur
Boudaren, Chaouki
Roisnel, Thierry
Bis(cytosinium) aqua­penta­chlorido­indate(III)
title Bis(cytosinium) aqua­penta­chlorido­indate(III)
title_full Bis(cytosinium) aqua­penta­chlorido­indate(III)
title_fullStr Bis(cytosinium) aqua­penta­chlorido­indate(III)
title_full_unstemmed Bis(cytosinium) aqua­penta­chlorido­indate(III)
title_short Bis(cytosinium) aqua­penta­chlorido­indate(III)
title_sort bis(cytosinium) aqua­penta­chlorido­indate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051970/
https://www.ncbi.nlm.nih.gov/pubmed/21522251
http://dx.doi.org/10.1107/S1600536811004235
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AT fantaziboubakeur biscytosiniumaquapentachloridoindateiii
AT boudarenchaouki biscytosiniumaquapentachloridoindateiii
AT roisnelthierry biscytosiniumaquapentachloridoindateiii

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