1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)

The asymmetric unit of the title compound, (C(15)H(15)N(2))[Ni(C(6)H(4)S(2))(2)], contains half each of two independent centrosymmetric anions and a single cation in a general position. The Ni(III) ions are coordinated by four S atoms in a square-planar geometry. The anions exhibit two packing modes...

Descripción completa

Detalles Bibliográficos
Autores principales: Dong, Yan-Jie, Kong, Xue-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051972/
https://www.ncbi.nlm.nih.gov/pubmed/21522268
http://dx.doi.org/10.1107/S1600536811004971
_version_ 1782199596253970432
author Dong, Yan-Jie
Kong, Xue-Jun
author_facet Dong, Yan-Jie
Kong, Xue-Jun
author_sort Dong, Yan-Jie
collection PubMed
description The asymmetric unit of the title compound, (C(15)H(15)N(2))[Ni(C(6)H(4)S(2))(2)], contains half each of two independent centrosymmetric anions and a single cation in a general position. The Ni(III) ions are coordinated by four S atoms in a square-planar geometry. The anions exhibit two packing modes, viz. stacked along the a axis in a face-to-face fashion with an alternate arrangement of anions and cations, and stacked in a side-by-side fashion, forming ribbons parallel to (011).
format Text
id pubmed-3051972
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30519722011-04-26 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III) Dong, Yan-Jie Kong, Xue-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(15)H(15)N(2))[Ni(C(6)H(4)S(2))(2)], contains half each of two independent centrosymmetric anions and a single cation in a general position. The Ni(III) ions are coordinated by four S atoms in a square-planar geometry. The anions exhibit two packing modes, viz. stacked along the a axis in a face-to-face fashion with an alternate arrangement of anions and cations, and stacked in a side-by-side fashion, forming ribbons parallel to (011). International Union of Crystallography 2011-02-16 /pmc/articles/PMC3051972/ /pubmed/21522268 http://dx.doi.org/10.1107/S1600536811004971 Text en © Dong and Kong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Yan-Jie
Kong, Xue-Jun
1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_full 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_fullStr 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_full_unstemmed 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_short 1-(4-Cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(III)
title_sort 1-(4-cyano­benz­yl)-3,5-dimethyl­pyridinium bis­(benzene-1,2-dithiol­ato)nickelate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051972/
https://www.ncbi.nlm.nih.gov/pubmed/21522268
http://dx.doi.org/10.1107/S1600536811004971
work_keys_str_mv AT dongyanjie 14cyanobenzyl35dimethylpyridiniumbisbenzene12dithiolatonickelateiii
AT kongxuejun 14cyanobenzyl35dimethylpyridiniumbisbenzene12dithiolatonickelateiii

Ejemplares similares