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Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate
In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]·0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd—N = 2.078 (8) Å] and methyl [Pd—C = 2.052 (9) Å] groups and the bidentate ligand 2-(1-{bis[2,4,6-tris(trif...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051981/ https://www.ncbi.nlm.nih.gov/pubmed/21522289 http://dx.doi.org/10.1107/S1600536811005277 |
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| author | Li, Liuzhong White, Peter S. Hao, Aiyou |
| author_facet | Li, Liuzhong White, Peter S. Hao, Aiyou |
| author_sort | Li, Liuzhong |
| collection | PubMed |
| description | In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]·0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd—N = 2.078 (8) Å] and methyl [Pd—C = 2.052 (9) Å] groups and the bidentate ligand 2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine (L). In L, one –CF(3) group is rotationally disordered between two orientations in a 1:1 ratio. The solvent molecule was treated as disordered between two positions related by an inversion center with occupancies fixed at 0.5. The crystal packing exhibits weak intermolecular C—H⋯F contacts. |
| format | Text |
| id | pubmed-3051981 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30519812011-04-26 Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate Li, Liuzhong White, Peter S. Hao, Aiyou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(CH(3))(C(26)H(14)F(18)NOP)(C(2)H(3)N)][SbF(6)]·0.5CH(2)Cl(2), the Pd(2+) cation has a distorted square-planar environment, being coordinated by the acetonitrile [Pd—N = 2.078 (8) Å] and methyl [Pd—C = 2.052 (9) Å] groups and the bidentate ligand 2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine (L). In L, one –CF(3) group is rotationally disordered between two orientations in a 1:1 ratio. The solvent molecule was treated as disordered between two positions related by an inversion center with occupancies fixed at 0.5. The crystal packing exhibits weak intermolecular C—H⋯F contacts. International Union of Crystallography 2011-02-23 /pmc/articles/PMC3051981/ /pubmed/21522289 http://dx.doi.org/10.1107/S1600536811005277 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Liuzhong White, Peter S. Hao, Aiyou Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title | Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title_full | Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title_fullStr | Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title_full_unstemmed | Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title_short | Acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(II) hexafluoridoantimonate dichloromethane hemisolvate |
| title_sort | acetonitrile[2-(1-{bis[2,4,6-tris(trifluoromethyl)phenyl]phosphanyloxy}-1-methylethyl)pyridine]methylpalladium(ii) hexafluoridoantimonate dichloromethane hemisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051981/ https://www.ncbi.nlm.nih.gov/pubmed/21522289 http://dx.doi.org/10.1107/S1600536811005277 |
| work_keys_str_mv | AT liliuzhong acetonitrile21bis246tristrifluoromethylphenylphosphanyloxy1methylethylpyridinemethylpalladiumiihexafluoridoantimonatedichloromethanehemisolvate AT whitepeters acetonitrile21bis246tristrifluoromethylphenylphosphanyloxy1methylethylpyridinemethylpalladiumiihexafluoridoantimonatedichloromethanehemisolvate AT haoaiyou acetonitrile21bis246tristrifluoromethylphenylphosphanyloxy1methylethylpyridinemethylpalladiumiihexafluoridoantimonatedichloromethanehemisolvate |