10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione

The dihydro­pyridine ring in the title compound, C(25)H(31)NO(4), adopts an envelope conformation with the methine C atom representing the flap. The cyclo­hexenone rings also adopt envelope conformations with the C atoms bearing the methyl C atoms representing the flaps. The phenolic hy­droxy group...

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Detalles Bibliográficos
Autores principales: Abdelhamid, Antar A., Mohamed, Shaaban K., Khalilov, Ali N., Gurbanov, Atash V., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051986/
https://www.ncbi.nlm.nih.gov/pubmed/21522483
http://dx.doi.org/10.1107/S1600536811006969
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author Abdelhamid, Antar A.
Mohamed, Shaaban K.
Khalilov, Ali N.
Gurbanov, Atash V.
Ng, Seik Weng
author_facet Abdelhamid, Antar A.
Mohamed, Shaaban K.
Khalilov, Ali N.
Gurbanov, Atash V.
Ng, Seik Weng
author_sort Abdelhamid, Antar A.
collection PubMed
description The dihydro­pyridine ring in the title compound, C(25)H(31)NO(4), adopts an envelope conformation with the methine C atom representing the flap. The cyclo­hexenone rings also adopt envelope conformations with the C atoms bearing the methyl C atoms representing the flaps. The phenolic hy­droxy group forms an intra­molecular hydrogen bond to one of the two keto O atoms. The hy­droxy group of the N-bonded alkyl chain forms an inter­molecular hydrogen bond to the other keto O atom of an adjacent mol­ecule. The latter hydrogen bond leads to the formation of a helical chain running along the b axis.
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spelling pubmed-30519862011-04-26 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione Abdelhamid, Antar A. Mohamed, Shaaban K. Khalilov, Ali N. Gurbanov, Atash V. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The dihydro­pyridine ring in the title compound, C(25)H(31)NO(4), adopts an envelope conformation with the methine C atom representing the flap. The cyclo­hexenone rings also adopt envelope conformations with the C atoms bearing the methyl C atoms representing the flaps. The phenolic hy­droxy group forms an intra­molecular hydrogen bond to one of the two keto O atoms. The hy­droxy group of the N-bonded alkyl chain forms an inter­molecular hydrogen bond to the other keto O atom of an adjacent mol­ecule. The latter hydrogen bond leads to the formation of a helical chain running along the b axis. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051986/ /pubmed/21522483 http://dx.doi.org/10.1107/S1600536811006969 Text en © Abdelhamid et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdelhamid, Antar A.
Mohamed, Shaaban K.
Khalilov, Ali N.
Gurbanov, Atash V.
Ng, Seik Weng
10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_full 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_fullStr 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_full_unstemmed 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_short 10-(2-Hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
title_sort 10-(2-hy­droxy­eth­yl)-9-(2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridine-1,8-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051986/
https://www.ncbi.nlm.nih.gov/pubmed/21522483
http://dx.doi.org/10.1107/S1600536811006969
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