(S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate

In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (−), the cyclo­hexa­none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C—N bond with a C(Ar)—C(Ar)—C—N torsion angle of −96.5 (5)°. Intermolecular N—H⋯O and O—...

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Detalles Bibliográficos
Autores principales: Hojahmat, Marhaba, Zheng, Guangrong, Siegler, Max, Parkin, Sean, Biermann, Manfred, Crooks, Peter A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051988/
https://www.ncbi.nlm.nih.gov/pubmed/21522475
http://dx.doi.org/10.1107/S1600536811006131
Descripción
Sumario:In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (−), the cyclo­hexa­none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C—N bond with a C(Ar)—C(Ar)—C—N torsion angle of −96.5 (5)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds are observed in the crystal structure.

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