(S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate

In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (−), the cyclo­hexa­none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C—N bond with a C(Ar)—C(Ar)—C—N torsion angle of −96.5 (5)°. Intermolecular N—H⋯O and O—...

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Detalles Bibliográficos
Autores principales: Hojahmat, Marhaba, Zheng, Guangrong, Siegler, Max, Parkin, Sean, Biermann, Manfred, Crooks, Peter A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051988/
https://www.ncbi.nlm.nih.gov/pubmed/21522475
http://dx.doi.org/10.1107/S1600536811006131
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author Hojahmat, Marhaba
Zheng, Guangrong
Siegler, Max
Parkin, Sean
Biermann, Manfred
Crooks, Peter A.
author_facet Hojahmat, Marhaba
Zheng, Guangrong
Siegler, Max
Parkin, Sean
Biermann, Manfred
Crooks, Peter A.
author_sort Hojahmat, Marhaba
collection PubMed
description In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (−), the cyclo­hexa­none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C—N bond with a C(Ar)—C(Ar)—C—N torsion angle of −96.5 (5)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-30519882011-04-26 (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate Hojahmat, Marhaba Zheng, Guangrong Siegler, Max Parkin, Sean Biermann, Manfred Crooks, Peter A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(15)ClNO(+)·C(4)H(5)O(6) (−), the cyclo­hexa­none ring adopts a chair conformation. The benzene ring is significantly twisted so that it is in an almost perpendicular position to the C—N bond with a C(Ar)—C(Ar)—C—N torsion angle of −96.5 (5)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2011-02-26 /pmc/articles/PMC3051988/ /pubmed/21522475 http://dx.doi.org/10.1107/S1600536811006131 Text en © Hojahmat et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hojahmat, Marhaba
Zheng, Guangrong
Siegler, Max
Parkin, Sean
Biermann, Manfred
Crooks, Peter A.
(S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title_full (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title_fullStr (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title_full_unstemmed (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title_short (S)-1-(2-Chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
title_sort (s)-1-(2-chloro­phen­yl)-2-oxocyclo­hexan-1-aminium d-tartrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051988/
https://www.ncbi.nlm.nih.gov/pubmed/21522475
http://dx.doi.org/10.1107/S1600536811006131
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