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Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 ...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051990/ https://www.ncbi.nlm.nih.gov/pubmed/21522255 http://dx.doi.org/10.1107/S1600536811004375 |
Sumario: | In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 (17) Å for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)° with the CuCl(2) plane. In the crystal, each pair of adjacent molecules is linked into a centrosymmetric dimer by N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by intermolecular C—H⋯N and C—H⋯Cl hydrogen bonds and weak slipped π–π stacking interactions between symmetry-related molecules, with an interplanar separation of 3.439 (19) Å and a centroid–centroid distance of 3.581 (19) Å. |
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