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Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)

In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 ...

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Autores principales: El Ghayati, Lhoussaine, El Ammari, Lahcen, Labd Taha, Mohamed, Tjiou, El Mostafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051990/
https://www.ncbi.nlm.nih.gov/pubmed/21522255
http://dx.doi.org/10.1107/S1600536811004375
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author El Ghayati, Lhoussaine
El Ammari, Lahcen
Labd Taha, Mohamed
Tjiou, El Mostafa
author_facet El Ghayati, Lhoussaine
El Ammari, Lahcen
Labd Taha, Mohamed
Tjiou, El Mostafa
author_sort El Ghayati, Lhoussaine
collection PubMed
description In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 (17) Å for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)° with the CuCl(2) plane. In the crystal, each pair of adjacent mol­ecules is linked into a centrosymmetric dimer by N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds and weak slipped π–π stacking inter­actions between symmetry-related mol­ecules, with an inter­planar separation of 3.439 (19) Å and a centroid–centroid distance of 3.581 (19) Å.
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spelling pubmed-30519902011-04-26 Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II) El Ghayati, Lhoussaine El Ammari, Lahcen Labd Taha, Mohamed Tjiou, El Mostafa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 (17) Å for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)° with the CuCl(2) plane. In the crystal, each pair of adjacent mol­ecules is linked into a centrosymmetric dimer by N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by inter­molecular C—H⋯N and C—H⋯Cl hydrogen bonds and weak slipped π–π stacking inter­actions between symmetry-related mol­ecules, with an inter­planar separation of 3.439 (19) Å and a centroid–centroid distance of 3.581 (19) Å. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051990/ /pubmed/21522255 http://dx.doi.org/10.1107/S1600536811004375 Text en © El Ghayati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
El Ghayati, Lhoussaine
El Ammari, Lahcen
Labd Taha, Mohamed
Tjiou, El Mostafa
Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title_full Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title_fullStr Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title_full_unstemmed Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title_short Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
title_sort dichlorido(3,5,5′-trimethyl-1,3′-bi-1h-pyrazole-κ(2) n (2),n (2′))copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051990/
https://www.ncbi.nlm.nih.gov/pubmed/21522255
http://dx.doi.org/10.1107/S1600536811004375
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