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Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II)
In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 ...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051990/ https://www.ncbi.nlm.nih.gov/pubmed/21522255 http://dx.doi.org/10.1107/S1600536811004375 |
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author | El Ghayati, Lhoussaine El Ammari, Lahcen Labd Taha, Mohamed Tjiou, El Mostafa |
author_facet | El Ghayati, Lhoussaine El Ammari, Lahcen Labd Taha, Mohamed Tjiou, El Mostafa |
author_sort | El Ghayati, Lhoussaine |
collection | PubMed |
description | In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 (17) Å for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)° with the CuCl(2) plane. In the crystal, each pair of adjacent molecules is linked into a centrosymmetric dimer by N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by intermolecular C—H⋯N and C—H⋯Cl hydrogen bonds and weak slipped π–π stacking interactions between symmetry-related molecules, with an interplanar separation of 3.439 (19) Å and a centroid–centroid distance of 3.581 (19) Å. |
format | Text |
id | pubmed-3051990 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30519902011-04-26 Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II) El Ghayati, Lhoussaine El Ammari, Lahcen Labd Taha, Mohamed Tjiou, El Mostafa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(9)H(12)N(4))], the Cu(II) atom exhibits a distorted square-planar coordination geometry involving two chloride ions and two N-atom donors from the bipyrazole ligand. The chelate ring including the Cu(II) atom is essentially planar, with a maximum deviation of 0.0181 (17) Å for one of the coordinated N atoms. This plane forms a dihedral angle of 30.75 (6)° with the CuCl(2) plane. In the crystal, each pair of adjacent molecules is linked into a centrosymmetric dimer by N—H⋯Cl hydrogen bonds. The crystal structure is stabilized by intermolecular C—H⋯N and C—H⋯Cl hydrogen bonds and weak slipped π–π stacking interactions between symmetry-related molecules, with an interplanar separation of 3.439 (19) Å and a centroid–centroid distance of 3.581 (19) Å. International Union of Crystallography 2011-02-12 /pmc/articles/PMC3051990/ /pubmed/21522255 http://dx.doi.org/10.1107/S1600536811004375 Text en © El Ghayati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers El Ghayati, Lhoussaine El Ammari, Lahcen Labd Taha, Mohamed Tjiou, El Mostafa Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2) N (2),N (2′))copper(II) |
title | Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2)
N
(2),N
(2′))copper(II) |
title_full | Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2)
N
(2),N
(2′))copper(II) |
title_fullStr | Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2)
N
(2),N
(2′))copper(II) |
title_full_unstemmed | Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2)
N
(2),N
(2′))copper(II) |
title_short | Dichlorido(3,5,5′-trimethyl-1,3′-bi-1H-pyrazole-κ(2)
N
(2),N
(2′))copper(II) |
title_sort | dichlorido(3,5,5′-trimethyl-1,3′-bi-1h-pyrazole-κ(2)
n
(2),n
(2′))copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051990/ https://www.ncbi.nlm.nih.gov/pubmed/21522255 http://dx.doi.org/10.1107/S1600536811004375 |
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