3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide

In the title molecular salt, C(31)H(34)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 80.47 (12) and 82.78 (12)° with the adjacent imidazole rings. The dihedral angle between the two terminal phenyl rings is 79.16 (13)°. In the crystal, the cations and anions are linked via C—H⋯...

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Autores principales: Haque, Rosenani A., Salman, Abbas Washeel, Nadarajan, Paremala, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051991/
https://www.ncbi.nlm.nih.gov/pubmed/21522396
http://dx.doi.org/10.1107/S1600536811005204
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author Haque, Rosenani A.
Salman, Abbas Washeel
Nadarajan, Paremala
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Salman, Abbas Washeel
Nadarajan, Paremala
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description In the title molecular salt, C(31)H(34)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 80.47 (12) and 82.78 (12)° with the adjacent imidazole rings. The dihedral angle between the two terminal phenyl rings is 79.16 (13)°. In the crystal, the cations and anions are linked via C—H⋯Br hydrogen bonds, forming supra­molecular chains along the c axis.
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spelling pubmed-30519912011-04-26 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide Haque, Rosenani A. Salman, Abbas Washeel Nadarajan, Paremala Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecular salt, C(31)H(34)N(4) (2+)·2Br(−), the central benzene ring makes dihedral angles of 80.47 (12) and 82.78 (12)° with the adjacent imidazole rings. The dihedral angle between the two terminal phenyl rings is 79.16 (13)°. In the crystal, the cations and anions are linked via C—H⋯Br hydrogen bonds, forming supra­molecular chains along the c axis. International Union of Crystallography 2011-02-16 /pmc/articles/PMC3051991/ /pubmed/21522396 http://dx.doi.org/10.1107/S1600536811005204 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Haque, Rosenani A.
Salman, Abbas Washeel
Nadarajan, Paremala
Hemamalini, Madhukar
Fun, Hoong-Kun
3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title_full 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title_fullStr 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title_full_unstemmed 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title_short 3,3′-Dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
title_sort 3,3′-dibenzyl-1,1′-(2,4,6-trimethyl-m-phenyl­enedimethyl­ene)diimidazol-3-ium dibromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051991/
https://www.ncbi.nlm.nih.gov/pubmed/21522396
http://dx.doi.org/10.1107/S1600536811005204
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