Cargando…

cis-Diaqua­bis­[dimethyl (phenyl­sulfonyl­imino)­phospho­nato]cobalt(II)

In the title diaqua­cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol­ecules which are in cis positions with respect to one an...

Descripción completa

Detalles Bibliográficos
Autores principales: Trush, Elizaveta A., Trush, Victor A., Sliva, Tetyana Yu., Konovalova, Irina S., Amirkhanov, Volodymyr M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051992/
https://www.ncbi.nlm.nih.gov/pubmed/21522293
http://dx.doi.org/10.1107/S1600536811006027
Descripción
Sumario:In the title diaqua­cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol­ecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octa­hedron. O—H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring mol­ecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio.